PHENYL AZIDE Chemical Properties

Melting point:

-27.5°C

Boiling point:

212.39°C (rough estimate)

Density 

1.0860

vapor density 

73.5 at 22-24 mm

refractive index 

1.5589

Flash point:

-12°C

storage temp. 

-20°C

color 

Pale-yellow oil

BRN 

742248

Safety Information

Hazard Codes 

F,Xn

Risk Statements 

11-19-48/20/21/22-38

Safety Statements 

16

RIDADR 

UN 2398 3 / PGII

WGK Germany 

3

PHENYL AZIDE Usage And Synthesis

Uses

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8

General Description

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

PHENYL AZIDE(622-37-7)Related Product Information

• 4-AZIDOBENZOIC ACID
• 2,6-BIS(4-AZIDOBENZYLIDENE)CYCLOHEXANONE
• 2,6-BIS(4-AZIDOBENZYLIDENE)-4-METHYLCYCLOHEXANONE
• PHENYL AZIDE
• 4-AZIDOPHENACYL BROMIDE
• 4-FLUORO-3-NITROPHENYL AZIDE
• 3,3'-DIAZIDODIPHENYL SULFONE
• 4-AZIDOPHENYL ISOTHIOCYANATE
• P-AZIDOPHENYL SULFONE
• 2-NITRO-5-AZIDOBENZOIC ACID
• 4-azidosalicylic acid N-hydroxysuccinimide ester
• N-HYDROXYSUCCINIMIDYL-4-AZIDOBENZOATE
• DTBPA
• SANPAH
• ANB-NOS
• 4-AZIDOANILINE HYDROCHLORIDE
• N-((4-azidophenyl)thio)phthalimide
• azapride