2-Iodo-4-methoxy-1-nitrobenzene Chemical Properties

Melting point:

68-73 °C

Boiling point:

352.1±27.0 °C(Predicted)

Density 

1.9259 (estimate)

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

form 

Crystals or Crystalline Powder

color 

Yellow to orange-brown

InChI

InChI=1S/C7H6INO3/c1-12-5-2-3-7(9(10)11)6(8)4-5/h2-4H,1H3

InChIKey

NLTAHTYBZZSCIT-UHFFFAOYSA-N

SMILES

C1([N+]([O-])=O)=CC=C(OC)C=C1I

Safety Information

Hazard Codes 

Xn

Risk Statements 

36-33-20/21/22

Safety Statements 

36/37-22

HS Code 

29093090

MSDS

• Language:English Provider:ACROS

2-Iodo-4-methoxy-1-nitrobenzene Usage And Synthesis

Chemical Properties

yellow to orange-brown crystals or

Synthesis

Silak reaction tube equipped with a magnetic stirrer was charged with 6.2 mg of silver sulfate,21.8 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline,39.4 mg of 2-nitro-5-methoxybenzoic acid and 45 mg of sodium iodide4 mL of dimethyl sulfoxide. The reaction was heated at 160 ° C for 24 hours with oxygen. After the reaction, distilled water was added to quench the reaction. Extraction with ethyl acetate 3 times, each time 10mL. The combined organic phases are concentrated; 35.2 mg of 2-Iodo-4-methoxy-1-nitrobenzene was obtained in a yield of 63 percent.

References

[1] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0133
[2] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
[3] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803

2-Iodo-4-methoxy-1-nitrobenzene(214279-40-0)Related Product Information

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