3-Chloropropyne Chemical Properties

Melting point:

<-50°C

Boiling point:

58 °C(lit.)

Density 

1.03 g/mL at 25 °C(lit.)

vapor pressure 

24.08-69.52kPa at 20-50℃

refractive index 

n20/D 1.456

Flash point:

7 °F

storage temp. 

2-8°C

solubility 

benzene: miscible

form 

clear liquid

color 

Colorless to Red to Green

Water Solubility 

Not miscible or difficult to mix with water.

Merck 

14,7810

BRN 

506005

Exposure limits

ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)

Dielectric constant

7.5599999999999996

LogP

1.3 at 25℃

CAS DataBase Reference

624-65-7(CAS DataBase Reference)

NIST Chemistry Reference

1-Propyne, 3-chloro-(624-65-7)

EPA Substance Registry System

1-Propyne, 3-chloro- (624-65-7)

Safety Information

Hazard Codes 

F,T,C

Risk Statements 

11-23/24/25-34-65-48/20-63

Safety Statements 

16-26-36/37/39-45-27-62

RIDADR 

UN 3286 3/PG 2

WGK Germany 

2

TSCA 

Yes

HazardClass 

3

PackingGroup 

II

HS Code 

29032990

MSDS

• Language:English Provider:3-Chloropropyne
• Language:English Provider:SigmaAldrich

3-Chloropropyne Usage And Synthesis

Chemical Properties

Light yellow liquid

Uses

Propargyl chloride was used to study emission spectra of dissociating propargyl chloride upon photoexcitation at 199 nm. It was used in the synthesis of novel tetraaryl analog of bisphenol A and triaryl analog of bisphenol A propargyl resins.

Uses

Intermediate in organic synthesis.

General Description

Propargyl chloride is an efficient propargylating agent. It generates propargyl radicals by the pulsed laser photolysis.

Hazard

Flammable, moderate fire risk.

Purification Methods

Purify the chloride by fractional distillation at atmospheric pressure. Note that a possible impurity is propargyl alcohol which has has b 114-115o/~760mm (see above). [Henry Chem Ber 8 398 1875.] HIGHLY TOXIC and FLAMMABLE.[Beilstein 1 IV 960.]

3-Chloropropyne(624-65-7)Related Product Information

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• Clomipramine
• Sulfuryl chloride
• Ammonium chloride
• Polyvinyl chloride
• Calcium chloride
• Propyne
• Sodium chloride
• Ferric chloride
• Choline chloride
• Sodium prop-2-yne-1-sulfonate
• Potassium chloride
• N-(4-CHLORO-2-BUTYNYL)PHTHALIMIDE
• Difluorochloromethane
• 3-CHLORO-3-METHYL-1-BUTYNE
• 3-CHLORO-1-BUTYNE
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• 1-CHLORO-2-PENTYNE