2-Amino-4-nitro anisidine
2-Amino-4-nitro anisidine Basic information
- Product Name:
- 2-Amino-4-nitro anisidine
- Synonyms:
-
- 1-Amino-2-methoxy-5-nitrobenzene
- 1-Methoxy-2-amino-4-nitrobenzene
- 2-methoxy-5-nitro-anilin
- 2-Methoxy-5-nitrobenzamine
- 2-methoxy-5-nitro-benzenamin
- 2-Methoxy-5-nitrobenzenamine
- 2-methoxy-5-nitro-Benzenamine
- 3-Amino-4-methoxynitrobenzene
- CAS:
- 99-59-2
- MF:
- C7H8N2O3
- MW:
- 168.15
- EINECS:
- 202-770-5
- Product Categories:
-
- Amines
- Building Blocks
- C7
- Chemical Synthesis
- Nitrogen Compounds
- Organic Building Blocks
- Intermediates of Dyes and Pigments
- Mol File:
- 99-59-2.mol
2-Amino-4-nitro anisidine Chemical Properties
- Melting point:
- 117-119 °C(lit.)
- Boiling point:
- 337.07°C (rough estimate)
- Density
- 1.2068
- vapor pressure
- 0.04Pa
- refractive index
- 1.6010 (estimate)
- Flash point:
- 119℃
- solubility
- 382mg/L in organic solvents at 20 ℃
- pka
- 2.42±0.10(Predicted)
- Colour Index
- 37130
- Water Solubility
- Slightly soluble. <0.01 g/100 mL at 19.5 ºC
- BRN
- 879620
- Stability:
- Stable, but may be moisture sensitive. Incompatible with water, acids, strong oxidizing agents, acid chlorides, acid anhydrides, chloroformates, liquid anisidine.
- LogP
- 1.16 at 23℃
- CAS DataBase Reference
- 99-59-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenamine, 2-methoxy-5-nitro-(99-59-2)
- IARC
- 3 (Vol. 27, Sup 7) 1987
- EPA Substance Registry System
- 2-Methoxy-5-nitroaniline (99-59-2)
Safety Information
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 26-36-45-36/37
- WGK Germany
- 2
- RTECS
- BZ7175000
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 2922290090
- Hazardous Substances Data
- 99-59-2(Hazardous Substances Data)
MSDS
- Language:English Provider:Azoamine Scarlet K
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
2-Amino-4-nitro anisidine Usage And Synthesis
Chemical Properties
orange to brown powder
Chemical Properties
5-Nitro-o-anisidine is an orange-red crystalline compound.
Uses
2-Methoxy-5-nitroaniline was used in the synthesis of 5-(9-acridinylamino)-p-anisidines via reaction with 9-anilinoacridines. It was also used in the synthesis of disazo disperse dyes containing nitro and methoxy groups, used for the dyeing of polyester fibre.
Definition
ChEBI: 2-methoxy-5-nitroaniline is a member of 4-nitroanisoles and a substituted aniline.
General Description
Orange-red needles or orange powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
2-Amino-4-nitro anisidine is incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides and chloroformates .
Fire Hazard
Flash point data for 2-Amino-4-nitro anisidine are not available. 2-Amino-4-nitro anisidine is probably combustible.
Flammability and Explosibility
Non flammable
Safety Profile
Suspected carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
Potential Exposure
5-Nitro-o-anisidine is a chemical intermediate in the production of C.I. Pigment red 23, which is used as a colorant for commodities, such as printing inks, interior latex paints; lacquers, rubber, plastics, floor coverings; paper coating; and textiles. It is also used with other C.I. coupling components to produce various hues of red, brown, yellow, and violet on cotton, silk, acetate and nylon.
Shipping
UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates.
Waste Disposal
Incineration (982℃, 2.0 seconds minimum) with scrubbing for nitrogen oxides abatement.
2-Amino-4-nitro anisidine Preparation Products And Raw materials
Preparation Products
Raw materials
2-Amino-4-nitro anisidineSupplier
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2-Amino-4-nitro anisidine(99-59-2)Related Product Information
- p-Anisidine
- o-Anisidine
- m-Anisidine
- 4-Nitroanthranilic acid
- 3,4-Difluoronitrobenzene
- 2-Methoxyethanol
- 2-METHOXY-6-NITRO-PHENYLAMINE
- 2-Methoxy-4-nitroaniline
- 3-Nitroanisole
- anisidine
- Nitrobenzene
- Azoic Diazo Component 1
- 4-Nitroanisole
- NITROGEN DIOXIDE
- Nitroaniline
- Amino resin,etherified
- 2-Amino-4-nitro anisidine
- Methoxy