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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic hafnium, silver, platinum >  Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane

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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Basic information

Product Name:
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
Synonyms:
  • PLATINUM DIVINYLTETRAMETHYLDISILOXANE COMPLEX, xylene solution
  • PlatinuM(o) 1,3 divinyl-1,1,3,3 tetraMethyldisiloxane
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, 20% Pt, Product of UMicore
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution in xylene, Pt ~2 %
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, Pt 2000 ppM
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, in poly(diMethylsiloxane)
  • PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE COMPLEX
  • PLATINUM-DIVINYLTETRAMETHYLDISILOXANE
CAS:
68478-92-2
MF:
C8H18OPtSi2
MW:
381.48
EINECS:
270-844-4
Product Categories:
  • Platinum
  • UVCBs-organometallic
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
Mol File:
68478-92-2.mol
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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Chemical Properties

Melting point:
12-13 °C
Boiling point:
138 °C
Density 
0.984 g/mL at 25 °C
vapor pressure 
7 mm Hg ( 21 °C)
refractive index 
1.4954
Flash point:
86 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Light yellow to Yellow to Green
Specific Gravity
0.984
Water Solubility 
Miscible with toluene, xylene, isopropyl alcohol, double-vinyl silicone oil and vinyl terminated poly(dimethylsiloxane). Immiscible with water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Stability:
Flammable. Incompatible with reducing agents, oxidizing agents. Contact with water yields hydrogen gas.
EPA Substance Registry System
Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes (68478-92-2)
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Safety Information

Hazard Codes 
T,Xi,Xn
Risk Statements 
61-10-20/21-37/38-41-62-36/37/38-38
Safety Statements 
53-16-26-36/37/39-45-36-36/37
RIDADR 
UN 1307 3/PG 3
WGK Germany 
3
TSCA 
Yes
HS Code 
28439000

MSDS

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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Usage And Synthesis

Description

Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a kind of yellow liquid with a chemical formula of O[Si(CH3)2CH=CH2]2Pt and a molecular weight of 381.48. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution (Pt-DVTMDS) has emerged as a novel organometallic compound with diverse applications in recent scientific research. This compound represents a coordination complex of platinum(0) and divinyl-1,1,3,3-tetramethyldisiloxane complex solution (DVTMDS). It has proven valuable in synthesizing diverse organometallic compounds, including gold(I)-DVTMDS and palladium(II)-DVTMDS. Furthermore, it has played a significant role in investigating chemical reactions, such as the catalytic hydrogenation of aldehydes and ketones theand oxidation of organic compounds. It was used as a precursor of the metallic phase to obtain a highly active electrochemical system Pt/SnO2 catalyst with a low metal load[1].

Chemical Properties

pale yellow solution

Uses

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a catalyst in the preparation of phenol functional silanes which are used as adhesion promoters.

Uses

Hydrosilylation Catalysts

General Description

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions.

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