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D-(+)-TURANOSE

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D-(+)-TURANOSE Basic information

Product Name:
D-(+)-TURANOSE
Synonyms:
  • 3-O-α-D-Glucopyranosyl-D-fructose
  • D-Turanose,98%
  • D-Fructose, 3-O-.alpha.-D-glucopyranosyl-
  • 3-o-à-d-glucopyranosyl-d-fructose
  • D-(+)-TURANOSE 98%
  • D-TURANOSETURANOSE
  • D-Turanose ,99%
  • 3-[ALPHA-D-GLUCOSIDO]-D-FRUCTOSE
CAS:
547-25-1
MF:
C12H22O11
MW:
342.3
EINECS:
208-918-5
Product Categories:
  • Basic Sugars (Mono & Oligosaccharides)
  • Biochemistry
  • 13C & 2H Sugars
  • Disaccharides
  • Sugars
  • Carbohydrates & Derivatives
  • Sugars, Carbohydrates & Glucosides
  • Glycon Biochem
Mol File:
547-25-1.mol
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D-(+)-TURANOSE Chemical Properties

Melting point:
170 °C (dec.)(lit.)
Boiling point:
397.76°C (rough estimate)
alpha 
D20 +27.3° +75.8° (c = 4 in water)
Density 
1.4149 (rough estimate)
refractive index 
75.5 ° (C=4, H2O)
storage temp. 
-20°C Freezer
solubility 
H2O: 0.1 g/mL, clear, colorless
pka
12.67±0.10(Predicted)
form 
Solid
color 
White
optical activity
+22 → +75
Water Solubility 
Soluble in water and methanol.
Merck 
14,9821
BRN 
93771
CAS DataBase Reference
547-25-1(CAS DataBase Reference)
EPA Substance Registry System
D-Fructose, 3-O-.alpha.-D-glucopyranosyl- (547-25-1)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
22-36/37/38-37/38-41
Safety Statements 
24/25-36/37/39-36-26
WGK Germany 
3
3-10
TSCA 
Yes
HS Code 
29400000

MSDS

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D-(+)-TURANOSE Usage And Synthesis

Chemical Properties

White Powder

Uses

D-Turanose is used as a carbon source by bacteria, fungi, and other organisms. It is involved in intracellular sugar signaling in plant cells.

Definition

ChEBI: A glycosylfructose isolated from Daphnia magna.

Purification Methods

Crystallise D(+)-turanose from H2O by addition of EtOH (its solubility is 5.3% in 95% EtOH). Form m 157o is obtained by crystallisation from hot MeOH, and mutarotates from +27.3o to [] 20D +88o (c 4, H2O). The phenylosazone crystallises from 15 parts of 95% EtOH with m 200-205o, [] D 24.5o mutarotating to +33o[24hours, c 0.82, pyridine/EtOH (4:6)]. [Pascu Methods in Carbohydrate Chemistry I 353 1962, Academic Press, Beilstein 17/7 V 213.] In D2O at 36o 1H NMR showed the following ratios: -pyranose (<4), -pyranose (39), -furanose (20) and -furanose (41)[Angyal Adv Carbohydr Chem 42 15 1984].

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