(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE CAS#: 64030-44-0

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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE

Basic information Safety Supplier Related

(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Basic information

Product Name:

(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE

Synonyms:

2-PyrrolidineMethanaMine,N-phenyl-, (2S)-
(S)-N-(Pyrrolidin-2-ylMethyl)aniline
(2S)-(Anilinomethyl)pyrrolidine
(S)-2-(Phenylaminomethyl)pyrrolidine
(S)-(+)-2-(Anilinomethyl)pyrrolidine 96%
(S)-2-(Anilinomethyl)pyrrolidine,99%e.e.
(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE
(S)-(+)-N-(2-PYRROLIDINOMETHYL)ANILINE

CAS:

64030-44-0

MF:

C11H16N2

MW:

176.26

Product Categories:

chiral
Asymmetric Synthesis
Synthetic Organic Chemistry
Asymmetric Synthesis
Chiral Catalysts, Ligands, and Reagents
Proline-Based Organocatalysts

Mol File:

64030-44-0.mol

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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Chemical Properties

Melting point:: 19°C
Boiling point:: 111-112 °C/0.55 mmHg (lit.)
Density: 1.046 g/mL at 25 °C (lit.)
refractive index: 1.5750
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: sol ether, THF.
pka: 10.52±0.10(Predicted)
form: clear liquid
color: Colorless to Yellow to Green
optical activity: [α]20/D +19°, c = 1 in ethanol
Sensitive: Air Sensitive
BRN: 472065
CAS DataBase Reference: 64030-44-0(CAS DataBase Reference)

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Safety Information

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: III
HS Code: 29339900

MSDS

Language:English Provider:SigmaAldrich
Language:English Provider:ALFA

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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Usage And Synthesis

Chemical Properties

Clear colorless viscous liquid

Synthesis

(S)-2-(Anilinomethyl)pyrrolidine is prepared by the reaction of (S)-N-(benzyloxycarbonyl)proline with ethyl chloroformate and N-methylmorpholine, aniline, hydrogenolysis with Pd/C, and reduction with LiAlH4 affords the title compound in 59% overall yield.

(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINESupplier

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