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5-Amino-1-naphthol

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5-Amino-1-naphthol Basic information

Product Name:
5-Amino-1-naphthol
Synonyms:
  • 1-Naphthalenol, 5-amino-
  • 1-Naphthol, 5-amino-
  • 5-amino-1-naphthaleno
  • 5-Amino-alpha-naphthol
  • C.I. 76650
  • 5-AMINO-1-NAPHTHOL
  • 5-HYDROXY-1-NAPHTHYLAMINE
  • 1-AMINO-5-HYDROXYNAPHTHALENE
CAS:
83-55-6
MF:
C10H9NO
MW:
159.18
EINECS:
201-486-9
Product Categories:
  • Intermediates of Dyes and Pigments
  • Organic Building Blocks
  • Oxygen Compounds
  • Phenols
Mol File:
83-55-6.mol
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5-Amino-1-naphthol Chemical Properties

Melting point:
190 °C (dec.) (lit.)
Boiling point:
284.68°C (rough estimate)
Density 
1.1202 (rough estimate)
refractive index 
1.6070 (estimate)
storage temp. 
-20°C Freezer
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
3.97(at 25℃)
form 
Solid
color 
Light Purple to Purple
CAS DataBase Reference
83-55-6(CAS DataBase Reference)
NIST Chemistry Reference
5-Amino-1-naphthol(83-55-6)
EPA Substance Registry System
1-Naphthalenol, 5-amino- (83-55-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29222990

MSDS

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5-Amino-1-naphthol Usage And Synthesis

Chemical Properties

pale purple to brown-purple crystalline powder

Uses

5-Amino-1-naphthol is used as a coupling component for azo dyes (coupling takes place ortho to the amino or hydroxyl group, or para to the hydroxyl group depending on the pH), and as an intermediate for sulfur dyes.

Preparation

1-Aminonaphthalene-5-sulfonic acid paste (Section 6.2) is added to molten sodium hydroxide at 200°C, and the reaction is completed by heating slowly to 250°C and maintaining this temperature for 3 h. After dilution and careful neutralization with hydrochloric acid, 5-amino-1-naphthol precipitates in 85 % yield (mp 192°C).

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