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N-HEXYLLITHIUM

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N-HEXYLLITHIUM Basic information

Product Name:
N-HEXYLLITHIUM
Synonyms:
  • n-Hexyllithium, 33 wt.% solution in n-hexane, AcroSeal
  • 1-Lithiohexane
  • 1-Hexyllithium
  • lithium,hexane
  • Lithium, hexyl-
  • HexyllithiuM, 2.5 M solution in Hexane, SpcSeal
  • HEXYLLITHIUM SOLUTION, IN HEXANE
  • HEXYLLITHIUM, SOLUTION IN HEXANE
CAS:
21369-64-2
MF:
C6H13Li
MW:
92.11
EINECS:
404-950-0
Product Categories:
  • Alkyl
  • Chemical Synthesis
  • Alkyl Metals
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Li (Lithium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
  • AlkylChemical Synthesis
  • Organic Bases
  • Organolithium
  • Organometallic Reagents
  • Synthetic Reagents
Mol File:
21369-64-2.mol
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N-HEXYLLITHIUM Chemical Properties

Boiling point:
69 °C
Density 
0.708 g/mL at 25 °C
vapor pressure 
26.9-39.3hPa at 20-35℃
Flash point:
16 °F
storage temp. 
2-8°C
color 
yellow-brown
Sensitive 
Moisture Sensitive
BRN 
3600261
Stability:
Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.
EPA Substance Registry System
Lithium, hexyl- (21369-64-2)
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Safety Information

Hazard Codes 
F,Xn,N,C
Risk Statements 
11-14/15-17-35-48/20-51/53-62-65-67
Safety Statements 
26-30-36/37/39-43-45-61-62-16-6
RIDADR 
UN 3394 4.2/PG 1
WGK Germany 
2
10-23
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090

MSDS

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N-HEXYLLITHIUM Usage And Synthesis

Description

n-Hexyllithium [21369-64-2], C6H13Li, Mr 92.11, r 0.766 g/cm3 is a pyrophoric colorless and viscous liquid in the neat state. It is commercially available as a 33 % solution in technical-grade hexane. Its reactivity resembles that of n-butyllithium and it can thus principally be used for the same applications. An advantage is that it does not form gaseous byproducts in deprotonation reactions and on hydrolysis, but liquid hexane instead.

Chemical Properties

often supplied as a deep yellow solution (ca 2M) in hexane

N-HEXYLLITHIUMSupplier

Lianyungang Jiezhong Pharmaceutical Technology Co., Ltd Gold
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13165449089
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2124455948@qq.com
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
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market03@meryer.com
Alfa Aesar
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400-6106006
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saleschina@alfa-asia.com
Energy Chemical
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021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com