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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information

Product Name:
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms:
  • Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
  • Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
  • DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
  • DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
  • BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
CAS:
12354-85-7
MF:
C20H30Cl4Rh210*
MW:
618.08
Product Categories:
  • metallocene
  • Catalysis and Inorganic Chemistry
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Chemical Synthesis
  • Rhodium
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Rh
Mol File:
12354-85-7.mol
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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties

Melting point:
>300°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
red
Water Solubility 
Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:
Hygroscopic
NIST Chemistry Reference
Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements 
26-36-S36-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000

MSDS

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis

Reaction

  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Supplier

Sinocompound Catalysts Co., Ltd. Gold
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0512-67216630 18962121273;
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LaaJoo Gold
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021-60702684 18516024827
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917-917-8888777 18691746767
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Shanghai PharmaPartner Co., Ltd. Gold
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