Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] CAS#: 12354-85-7

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Basic information Reaction Safety Supplier Related

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information

Product Name:

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Synonyms:

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER

CAS:

12354-85-7

MF:

C20H30Cl4Rh210*

MW:

618.08

Product Categories:

metallocene
Catalysis and Inorganic Chemistry
Catalysts for Organic Synthesis
Classes of Metal Compounds
Chemical Synthesis
Rhodium
Homogeneous Catalysts
Metal Complexes
Rh (Rhodium) Compounds
Synthetic Organic Chemistry
Transition Metal Compounds
Rh

Mol File:

12354-85-7.mol

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties

Melting point:: >300°C
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: crystal
color: red
Water Solubility: Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:: Hygroscopic
NIST Chemistry Reference: Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

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Safety Information

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements: 26-36-S36-S26-24/25
WGK Germany: 3
TSCA: No
HS Code: 28439000

MSDS

Language:English Provider:ACROS
Language:English Provider:SigmaAldrich
Language:English Provider:ALFA

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis

Reaction

Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
Catalyst used in the asymmetric transfer hydrogenation of imines in water.
Facile rhodium-catalyzed synthesis of fluorinated pyridines.
Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Supplier

Sinocompound Catalysts Co., Ltd. Gold

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