Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] CAS#: 12354-85-7

ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Basic information Reaction Safety Supplier Related

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information

Product Name:

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Synonyms:

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER

CAS:

12354-85-7

MF:

C20H30Cl4Rh210*

MW:

618.08

Product Categories:

metallocene
Catalysis and Inorganic Chemistry
Catalysts for Organic Synthesis
Classes of Metal Compounds
Chemical Synthesis
Rhodium
Homogeneous Catalysts
Metal Complexes
Rh (Rhodium) Compounds
Synthetic Organic Chemistry
Transition Metal Compounds
Rh

Mol File:

12354-85-7.mol

Less

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties

Melting point:: >300°C
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: crystal
color: red
Water Solubility: Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:: Hygroscopic
NIST Chemistry Reference: Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

Less

Safety Information

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements: 26-36-S36-S26-24/25
WGK Germany: 3
TSCA: No
HS Code: 28439000

MSDS

Language:English Provider:ACROS
Language:English Provider:SigmaAldrich
Language:English Provider:ALFA

Less

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis

Reaction

Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
Catalyst used in the asymmetric transfer hydrogenation of imines in water.
Facile rhodium-catalyzed synthesis of fluorinated pyridines.
Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Supplier

Sinocompound Catalysts Co., Ltd. Gold

Tel: 0512-67216630 67216634
Email: sales@sinocompound.com

LaaJoo Gold

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com

Shaanxi Rock New Materials Co., Ltd. Gold

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com

Panjin Greenchem Technology Co., Ltd. Gold

Tel: 13121959385 13121959385
Email: chemrocking@bjgreenchem.com

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Email: jkinfo@jkchemical.com

Less