Basic information Safety Supplier Related

(1S)-(+)-CAMPHORQUINONE

Basic information Safety Supplier Related

(1S)-(+)-CAMPHORQUINONE Basic information

Product Name:
(1S)-(+)-CAMPHORQUINONE
Synonyms:
  • 3-dione,1,7,7-trimethyl-,(1S)-Bicyclo[2.2.1]heptane-2
  • 7,7-trimethyl-3-dion(1s)-bicyclo[2.2.1]heptane-1
  • S-(+)-CAMPHORQUINONE
  • CAMPHORQUINONE, -S-(+)-
  • (+)-CAMPHORQUINONE
  • L-(+)-CAMPHORQUINONE
  • L-CAMPHORQUINONE
  • L-2, 3-BORNANEDIONE
CAS:
2767-84-2
MF:
C10H14O2
MW:
166.22
EINECS:
220-446-1
Product Categories:
  • Bicyclic Monoterpenes
  • Biochemistry
  • Terpenes
  • Ring Systems
Mol File:
2767-84-2.mol
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(1S)-(+)-CAMPHORQUINONE Chemical Properties

Melting point:
197-201 °C(lit.)
alpha 
+100° (20/D)(c=1.9, C6H5CH3)
Boiling point:
234.44°C (rough estimate)
Density 
0.9817 (rough estimate)
refractive index 
1.4859 (estimate)
form 
powder to crystal
color 
White to Yellow to Orange
optical activity
[α]20/D +100°, c = 1.9 in toluene
BRN 
2613999
CAS DataBase Reference
2767-84-2(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-, (1S,4R)- (2767-84-2)
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
10
TSCA 
Yes
HS Code 
29142900

MSDS

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(1S)-(+)-CAMPHORQUINONE Usage And Synthesis

Chemical Properties

YELLOW POWDER

Uses

Chiral starting material.

Definition

ChEBI: (1S)-bornane-2,3-dione is a bornane-2,3-dione. It is an enantiomer of a (1R)-bornane-2,3-dione.

Purification Methods

It can be purified by steam distillation, recrystallisation (yellow prisms) from EtOH, *C6H6 or Et2O/pet ether and it can be sublimed in a vacuum. The (±)-quinone forms needles from EtOH, m 197-198o, 203o. [Buxtorf & Flatt Helv Chim Acta 13 1026 1930, Asahena et al. Chem Ber 67 1432 1934, Beiltein 7 I 325.]

(1S)-(+)-CAMPHORQUINONESupplier

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