(1S)-(+)-CAMPHORQUINONE Chemical Properties

Melting point:

197-201 °C(lit.)

Boiling point:

234.44°C (rough estimate)

alpha 

+100° (20/D)(c=1.9, C6H5CH3)

Density 

0.9817 (rough estimate)

refractive index 

1.4859 (estimate)

form 

powder to crystal

color 

White to Yellow to Orange

optical activity

[α]20/D +100°, c = 1.9 in toluene

BRN 

2613999

CAS DataBase Reference

2767-84-2(CAS DataBase Reference)

EPA Substance Registry System

Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-, (1S,4R)- (2767-84-2)

Safety Information

Safety Statements 

22-24/25

WGK Germany 

3

F 

10

TSCA 

Yes

HS Code 

29142900

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

(1S)-(+)-CAMPHORQUINONE Usage And Synthesis

Chemical Properties

YELLOW POWDER

Uses

Chiral starting material.

Definition

ChEBI: (1S)-bornane-2,3-dione is a bornane-2,3-dione. It is an enantiomer of a (1R)-bornane-2,3-dione.

Purification Methods

It can be purified by steam distillation, recrystallisation (yellow prisms) from EtOH, *C6H6 or Et2O/pet ether and it can be sublimed in a vacuum. The (±)-quinone forms needles from EtOH, m 197-198o, 203o. [Buxtorf & Flatt Helv Chim Acta 13 1026 1930, Asahena et al. Chem Ber 67 1432 1934, Beiltein 7 I 325.]

(1S)-(+)-CAMPHORQUINONE(2767-84-2)Related Product Information

• 2,3-HEXANEDIONE
• 3,5-Dimethyl-1,2-cyclopentanedione
• 3-METHYLCYCLOHEXANE-1,2-DIONE
• (-)-CAMPHOR
• 3-ethyl-2-hydroxy-4-methylcyclopent-2-en-1-one
• 3,4-dimethyl 2-hydroxy-2-cyclopenten-1-one
• 3,4-Hexanedione
• 5-METHYL-2,3-HEXANEDIONE
• 2,4,4-TRIMETHYLCYCLOPENTANONE
• (1S)-(+)-CAMPHORQUINONE
• 1,2-Cyclohexanedione
• 3-Methyl-1,2-cyclopentanedione
• (1S,E)-(-)-CAMPHORQUINONE 3-OXIME
• (+/-)-CAMPHORQUINONE,CAMPHORQUINONE,DL-CAMPHORQUINONE,RAC-CAMPHORQUINONE
• DL-CAMPHORQUINONE
• R-(-)-CAMPHORQUINONE,D-(-)-Camphorquinone,98%,(-)-CAMPHORQUINONE,(1R)-(-)-CAMPHORQUINONE,D-CAMPHORQUINONE,D-(-)-CAMPHORQUINONE,CAMPHORQUINONE, -R-(-)-
• Camphor
• DL-Camphor