ChemicalBook > Product Catalog > Organic Chemistry > Organometalate > (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Basic information
- Product Name:
- (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
- Synonyms:
-
- (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
- (S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-
- (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
- (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
- (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride
- (S,S)Salen AI
- Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)
- (s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride
- CAS:
- 307926-51-8
- MF:
- C36H52AlClN2O2
- MW:
- 607.254
- Product Categories:
-
- Jacobsen Metal
- Mol File:
- 307926-51-8.mol
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Chemical Properties
- Melting point:
- >350 °C(lit.)
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- Powder
- color
- yellow
- InChIKey
- KGVBCKDZFMLRMA-RUIQGICGSA-K
- SMILES
- CC(C)(C)c1cc2\C=N\[C@H]3CCCC[C@@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Usage And Synthesis
Reaction
Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes.
Uses
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
- In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
- In the cyanation of α,β-unsaturated imides to yield saturated imides.
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&Supplier
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