N-Methyl-N-nitrosotoluene-4-sulphonamide Chemical Properties

Melting point:

~58 °C

Boiling point:

320.5±35.0 °C(Predicted)

Density 

1.3844 (rough estimate)

refractive index 

1.5690 (estimate)

storage temp. 

2-8°C

solubility 

Chloroform (Slightly), Dichloromethane (Sparingly), DMSO (Slightly), Ethyl Acetate

pka

-19.25±0.70(Predicted)

form 

Solid

color 

Pale Yellow to Yellow

Merck 

13,9621

Stability:

Stable, but heat sensitive; may also be light sensitive. Incompatible with strong oxidizing agents, alkalies.

CAS DataBase Reference

80-11-5(CAS DataBase Reference)

NIST Chemistry Reference

N-methyl-n-nitroso, p-toluene sulfonamide(80-11-5)

EPA Substance Registry System

Benzenesulfonamide, N,4-dimethyl-N-nitroso- (80-11-5)

Safety Information

Hazard Codes 

E,Xi,Xn

Risk Statements 

2-36/37/38-43-20/21/22

Safety Statements 

15-26-35-36/37-36

RIDADR 

UN 3234 4.1/PG 2

WGK Germany 

2

RTECS 

XT5950000

HazardClass 

6.1(b)

PackingGroup 

III

HS Code 

29350090

Hazardous Substances Data

80-11-5(Hazardous Substances Data)

MSDS

• Language:English Provider:Diazald
• Language:English Provider:SigmaAldrich

N-Methyl-N-nitrosotoluene-4-sulphonamide Usage And Synthesis

Chemical Properties

pale yellow crystalline powder

Uses

N-Methyl-N-nitroso-p-toluenesulfonamide is Diazomethane precursor.

Uses

In the laboratory preparation of diazomethane. Directions for use: de Boer, Backer, Rec. Trav. Chim. 73, 232 (1954).

Definition

ChEBI: N,4-dimethyl-N-nitrosobenzenesulfonamide is a sulfonamide.

Purification Methods

Crystallise diazald from *benzene by addition of pet ether and store it in a refrigerator. It is soluble in most organic solvents and liberates diazomethane on treatment with alkali. Store it in the cold. [deBoer & Backer Org Synth 34 96 1954, Beilstein 11 I 29.]

N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)Related Product Information

• p-Toluenesulfonamide
• Methanol
• Kresoxim-methyl
• Tosyl azide
• Methyl acetate
• Basic Violet 1
• SODIUM NITROPRUSSIDE
• Tosylmethyl isocyanide
• Methylparaben
• Acetonitrile
• 2-Methylbenzotrifluoride
• Toluenesulfonamide
• Sulfanilamide
• Methyl acrylate
• NITROSOGUANIDINE
• Paraquat dichloride
• 4-Nitro-N-methylphthalimide
• N-((3R,4R)-1-benzyl-4-methylpiperidin-3-yl)-N-methyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine