Zirconium sulphate
Zirconium sulphate Basic information
- Product Name:
- Zirconium sulphate
- Synonyms:
-
- disulfatozirconicacid
- Sulfuricacid,zirconium(4+)salt(2:1)
- sulfuricacid,zirconium(4++)salt(2:1)
- Bis(sulfonylbisoxy)zirconium(IV)
- Nsc115915
- Wln: zr2 S-o4*2
- zirconium tanning agent
- zirconium(iv)sulfate(1:2)
- CAS:
- 14644-61-2
- MF:
- O8S2Zr
- MW:
- 283.35
- EINECS:
- 238-694-4
- Product Categories:
-
- metal sulfate
- Metal and Ceramic Science
- Inorganics
- Salts
- Zirconium Salts
- Mol File:
- 14644-61-2.mol
Zirconium sulphate Chemical Properties
- Melting point:
- 410°C
- Density
- 3.22
- solubility
- H2O: slightly soluble(lit.)
- color
- white hygroscopic crystals, crystalline
- Water Solubility
- 52.5g/100g solution H2O (18°C); deposits solid with elementary composition 4ZrO2 · 3SO3 · 15H2O, on standing at ambient temp [MER06]
- Merck
- 13,10235
- InChIKey
- ZXAUZSQITFJWPS-UHFFFAOYSA-J
- CAS DataBase Reference
- 14644-61-2(CAS DataBase Reference)
- EPA Substance Registry System
- Zirconium sulfate (14644-61-2)
Safety Information
- Hazard Codes
- C,Xi
- Risk Statements
- 34-36/37/38
- Safety Statements
- 26-27-36/37/39-45
- RIDADR
- UN 3264 8/PG 3
- RTECS
- ZH9100000
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- Hazardous Substances Data
- 14644-61-2(Hazardous Substances Data)
MSDS
- Language:English Provider:Zirconium sulphate
- Language:English Provider:SigmaAldrich
Zirconium sulphate Usage And Synthesis
Chemical Properties
white crystal(s) [STR93]
Physical properties
Anhydrous sulfate is a microcrystalline hygroscopic solid; density 3.22 g/cm3; decomposes at 410°C; soluble in water.
The tetrahydrate, Zr(SO4)2?4H2O, is a white crystalline solid; orthorhombic crystals; loses three molecules of water between 100 and 150°C; becomes anhydrous at 380°C; soluble in water, 52.5 g/100g solution; the solution deposits a solid on standing; the aqueous solution is strongly acidic, decomposed by bases or on heating.
Uses
Zirconium sulfate [Zr(SO4)2] is an ingredient in lubricants that do not disintegrate at hightemperatures. It is also used for tanning leather to make it white and as a chemical reagent and catalyst in chemical laboratories.
Preparation
Zirconium sulfate is prepared by the action of sulfuric acid on zirconium hydroxide: Zr(OH)4 + 2H2SO4 → Zr(SO4)2 + 4H2O
Also, it is prepared by treating zirconyl chloride with hot concentrated sulfuric acid: ZrOCl2 + 2H2SO4 → Zr(SO4)2 + H2O + 2HCl.
General Description
Anhydrous Zirconium sulphate is a colorless microcrystalline solid. Zirconium sulphate is also obtained as a white crystalline tetrahydrate, ZrSO4.4H2O. Both forms are soluble in water and noncombustible. Zirconium sulphate is corrosive to aluminum. Zirconium sulphate is used in chemical analysis, as an additive for lubricants, and for many other uses.
Air & Water Reactions
Water soluble.
Reactivity Profile
Zirconium sulphate is a weak oxidizing agent. Water solutions are acidic and corrosive to aluminum and other metals
Health Hazard
Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.
Fire Hazard
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
Flammability and Explosibility
Non flammable
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. A corrosive. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also SULFATES and ZIRCONIUM COMPOUNDS.
Zirconium sulphate Preparation Products And Raw materials
Preparation Products
Raw materials
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Zirconium sulphate(14644-61-2)Related Product Information
- Neomycin sulfate
- Atropine sulfate
- Calcium sulfite
- SULFATE STANDARD
- Ammonium sulfate
- Barium sulfate
- alumium polysulfate
- Ferrous sulfate heptahydrate
- Colistin sulfate
- SODIUM SULFATE
- Aluminum nitrate
- Zirconium dioxide
- BISMUTH SULFATE
- ZIRCONIUM SULFATE HYDRATE, 99.99%,ZIRCONIUM SULFATE HYDRATE
- Zirconium
- Zirconium sulfate tetrahydrate, 99.99%,ZIRCONIUM SULFATE 4H2O,Zirconium(Ⅳ)sulfate tetrahydrate,ZIRCONIUM SULFATE TETRAHYDRATE
- ZIRCONIUM SULFATE OXIDE HYDRATE
- Zirconium sulfate basic