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Barium isopropoxide

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Barium isopropoxide Basic information

Product Name:
Barium isopropoxide
Synonyms:
  • Bariumi-propoxide(~20%inisopropanol)
  • Bariumi-propoxide,drypowder
  • Barium diisopropoxide
  • Bis(isopropoxy) barium
  • Diisopropoxybarium
  • Barium i-propoxide (approx. 20% in isopropanol)
  • bariuM propan-2-olate
  • Barium isopropoxide powder, 99.9% trace metals basis
CAS:
24363-37-9
MF:
C6H14BaO2
MW:
255.5
Product Categories:
  • Barium
  • Micro/Nanoelectronics
  • Solution Deposition Precursors
  • metal alkoxide
Mol File:
24363-37-9.mol
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Barium isopropoxide Chemical Properties

Melting point:
200 °C (dec.)(lit.)
Boiling point:
82°C
Density 
0,89 g/cm3
Flash point:
12°C
form 
powder
color 
Brown to yellow
Specific Gravity
0.89
Water Solubility 
Soluble in alcohols, ketones and esters. Reacts with water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Exposure limits
ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/22
Safety Statements 
28
RIDADR 
UN 3205 4.2/PG 3
WGK Germany 
1
TSCA 
No
HazardClass 
4.2
PackingGroup 
III
HS Code 
2805191000

MSDS

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Barium isopropoxide Usage And Synthesis

Uses

Barium isopropoxide is used in nano-materials and thin Films, catalysis synthesis, ferroelectric metals. It is also used as organic intermediate.

Application

For preparation of bimetallic Ba-Nb and Ba-Zr alkoxides.[1] Asymmetric aldol reactions are promoted by a novel catalyst prepared from Ba(O-i-Pr)2.[2]
It may be used as a catalyst for one pot preparation of symmetrical 1,5-diketones.[3] Sol gel synthesis of ternary compound, Ba3 Li 2Ti8 O20 can be carried out by precursor reactants, barium isopropoxide, titanium isopropoxide and lithium acetate. [4]

reaction suitability

core: barium

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