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5-Amino-2-bromopyridine

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5-Amino-2-bromopyridine Basic information

Product Name:
5-Amino-2-bromopyridine
Synonyms:
  • 2-Bromo-5-aminoyridine
  • 6-BROMOPYRIDIN-3-AMINE
  • TIMTEC-BB SBB005540
  • TIMTEC-BB SBB003823
  • LABOTEST-BB LT00129606
  • 2-BROMO-5-AMINOPYRIDINE
  • 5-BROMO-2-AMINOPYRIDINE
  • 5-AMINO-2-BROMOPYRIDINE
CAS:
13534-97-9
MF:
C5H5BrN2
MW:
173.01
EINECS:
628-541-3
Product Categories:
  • Building Blocks
  • C5
  • C5 to C6
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Chemical Amines
  • Bromopyridines
  • Halopyridines
  • Aromatics
  • C5Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Amino-pyridine series
  • pyridines
  • Amines
  • blocks
  • Bromides
  • Pyridine
  • pyridine derivative
  • Amines and Anilines
  • Heterocycles
  • pharmacetical
  • Pyridine series
  • Boronic Acid
Mol File:
13534-97-9.mol
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5-Amino-2-bromopyridine Chemical Properties

Melting point:
75 °C
Boiling point:
180 °C
Density 
1.6065 (rough estimate)
refractive index 
1.5182 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Methanol
pka
1.87±0.10(Predicted)
form 
Powder
color 
Beige to brown-black
BRN 
109102
CAS DataBase Reference
13534-97-9(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
10
HazardClass 
IRRITANT
PackingGroup 
III
HS Code 
29333990

MSDS

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5-Amino-2-bromopyridine Usage And Synthesis

Chemical Properties

Light yellow needles

Uses

3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.

General Description

3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.

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