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(2-Butenyl)chloropalladium dimer

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(2-Butenyl)chloropalladium dimer Basic information

Product Name:
(2-Butenyl)chloropalladium dimer
Synonyms:
  • CROTYLPALLADIUM CHLORIDE DIMER
  • Dichloro-(1-methylallyl)-dipalladium
  • (2-Butenyl)chloropalladium dimer
  • (2-Butenyl)chloropalladium dimer >=97%
  • Dichlorobis(1-methylallyl)dipalladium
  • (1-METHYLALLYL)PALLADIUMCHLORIDEDIMER,99%
  • Crotylpalladiumchloridedimer,99%
  • CrotylpalladiuM chloride diMer,98%
CAS:
12081-22-0
MF:
C8H14Cl2Pd2
MW:
393.94
Product Categories:
  • Pd
  • organometallic complexes
Mol File:
12081-22-0.mol
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(2-Butenyl)chloropalladium dimer Chemical Properties

Melting point:
133-140 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
yellow
Sensitive 
air sensitive
InChI
InChI=1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;
InChIKey
NTFUUQYNUUTALG-HYTOEPEZSA-L
SMILES
C(=C/C)\C[Pd]Cl.C(=C/C)\C[Pd]Cl
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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(2-Butenyl)chloropalladium dimer Usage And Synthesis

Uses

Catalyst for:

  • Enantioselective elimination of palladium hydride
  • Non-covalent anchoring of catalysts to silica supports
  • Allylations of cyanoacetates
  • Enantioselective nucleophilic substitutions

Reactant for:
  • Allylic alkylation reactions
  • Preparation of phosphane-functionalized carbosilane dendrimers

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