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TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE

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TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Basic information

Product Name:
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE
Synonyms:
  • TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE
  • TRI-N-BUTYLPHOSPHINE TETRAFLUOROBORATE,&
  • Tri-n-butylphosphoniumtetrafluoroborate,99%
  • tributylphosphine tetrafluoroborate
  • Tributylphosphonium tetrafluoroborate
  • Tributylphosphine tetrafluoroborate 97%
  • [n-Bu3PH]BF4
  • Tributylphosphine tetrafluoroborate,97%
CAS:
113978-91-9
MF:
C12H28BF4P
MW:
290.13
Product Categories:
  • Achiral Phosphine
  • Alkyl Phosphine
  • P-BF4
  • organophosphine salt
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds
Mol File:
113978-91-9.mol
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TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Chemical Properties

Melting point:
50-53 °C (lit.)
Flash point:
>221 °F
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
InChI
InChI=1S/C12H27P.BF4/c1-4-7-10-13(11-8-5-2)12-9-6-3;2-1(3,4)5/h4-12H2,1-3H3;/q;-1/p+1
InChIKey
NCHAZLRRIGGCER-UHFFFAOYSA-O
SMILES
[B-](F)(F)(F)F.[PH+](CCCC)(CCCC)CCCC
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
2931599090

MSDS

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TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Usage And Synthesis

Reaction

  1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
  2. Catalyst in Baylis-Hillman reactions.
  3. Azide reductions.
  4. Acylation of alcohols by anhydrides.
  5. Ligand for formate reduction of allyl carbonates.
  6. Synthesis of aromatic nitriles via Pd C-H functionalization. 

General Description

May contain approximately 5% of other butyl isomers.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATESupplier

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