Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Basic information
- Product Name:
- Tris(2-phenylpyridine)iridium (Ir(ppy)3)
- Synonyms:
-
- Tris(2-phenylpyridinato) iridium(III),98+%
- TRIS(2-PHENYLPYRIDINE)IRIDIUM
- TRIS(2-PHENYLPYRIDINE)IRIDIUM (III)
- Tris[2-phenylpyridinato-C2,N]iridium(III) sublimed grade
- Tris(2-phenylpyridine)iridium (Ir(ppy)3)
- iridium(3+),2-phenylpyridine
- fac-Tris(2-phenylpyridine)iridium
- Iridium, tris(2-phenylpyidine)
- CAS:
- 94928-86-6
- MF:
- C33H24IrN3
- MW:
- 654.79
- EINECS:
- 635-640-5
- Product Categories:
-
- Electronic Chemicals
- electronic
- Classes of Metal Compounds
- Highly Purified Reagents
- Ir (Iridium) Compounds
- Other Categories
- Refined Products by Sublimation
- Transition Metal Compounds
- olde Materials
- oled materials
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
- OLED
- 94928-86-6
- Mol File:
- 94928-86-6.mol
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties
- Melting point:
- 328°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
- CAS DataBase Reference
- 94928-86-6(CAS DataBase Reference)
- Absorption
- λmax?282, 377 nm?in THF
MSDS
- Language:English Provider:ALFA
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Usage And Synthesis
Applications
Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.
Reactions
- Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
- Photocatalyst for trifluoromethylation of alkenes and alkynes
- Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
- Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
- Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
- Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides
Description
Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Chemical Properties
Light yellow to red solid
Uses
suzuki reaction
Uses
Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.
General Description
Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.
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Tris(2-phenylpyridine)iridium (Ir(ppy)3)(94928-86-6)Related Product Information
- Iridium
- Pyridine sulfur trioxide
- 2-Phenylpyridine
- TRIPHENYLBORANE
- Triphenylphosphine
- BIS-Tris
- BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
- 2,4,6-Collidine
- Triphenylphosphine oxide
- Triphenylmethyl Chloride
- Tricine
- Tris(hydroxymethyl)aminomethane
- Thieno[3,2-b]thiophene
- tris(2-carboxyethyl)phosphine
- Tris(2-chloroethyl) phosphate
- tris-(1,10-phenanthroline)ruthenium
- N,N'- Dibutylquinacridone
- Coumarin 6