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Tris(2-phenylpyridine)iridium (Ir(ppy)3)

Basic information Applications Reactions Safety Supplier Related

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Basic information

Product Name:
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Synonyms:
  • Tris(2-phenylpyridinato) iridium(III),98+%
  • TRIS(2-PHENYLPYRIDINE)IRIDIUM
  • TRIS(2-PHENYLPYRIDINE)IRIDIUM (III)
  • Tris[2-phenylpyridinato-C2,N]iridium(III) sublimed grade
  • Tris(2-phenylpyridine)iridium (Ir(ppy)3)
  • iridium(3+),2-phenylpyridine
  • fac-Tris(2-phenylpyridine)iridium
  • Iridium, tris(2-phenylpyidine)
CAS:
94928-86-6
MF:
C33H24IrN3
MW:
654.79
EINECS:
635-640-5
Product Categories:
  • Electronic Chemicals
  • electronic
  • Classes of Metal Compounds
  • Highly Purified Reagents
  • Ir (Iridium) Compounds
  • Other Categories
  • Refined Products by Sublimation
  • Transition Metal Compounds
  • olde Materials
  • oled materials
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
Mol File:
94928-86-6.mol
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties

Melting point:
328°C
form 
Powder
color 
yellow
Sensitive 
air sensitive
CAS DataBase Reference
94928-86-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
28439000

MSDS

  • Language:English Provider:ALFA
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Usage And Synthesis

Applications

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.

Reactions

  1. Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
  2. Photocatalyst for trifluoromethylation of alkenes and alkynes
  3. Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
  4. Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
  5. Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
  6. Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides

Chemical Properties

Light yellow to red solid

Uses

suzuki reaction

Tris(2-phenylpyridine)iridium (Ir(ppy)3)Supplier

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