Basic information Safety Supplier Related

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Basic information Safety Supplier Related

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Basic information

Product Name:
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms:
  • Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • (S)-Ru(OAc)2(BINAP)
  • Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]
  • Ru(OAc)2[(S)-binap]
  • RU(OAC)2[(S)-BINAP]
  • Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)/ (S)-Ru(OAc)2(BINAP)
  • Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-
  • Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthy...
CAS:
261948-85-0
MF:
C48H40O4P2Ru
MW:
843.86
Product Categories:
  • Ru
Mol File:
261948-85-0.mol
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Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
pale yellow
Sensitive 
air sensitive
InChIKey
XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES
CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1
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Safety Information

WGK Germany 
3
HS Code 
2843.90.0000
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Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Usage And Synthesis

Uses

(S)-Ru(OAc)2(BINAP) is a catalyst.

Reactions

1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the
hydrogenation of a wide range of substrates.
2. Catalyst used in the synthesis of β-amino acids by hydrogenation.

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)Supplier

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