ChemicalBook > Product Catalog > Organic Chemistry > Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Basic information
- Product Name:
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
- Synonyms:
-
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
- Rh2(S-PTAD)4
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Rh2(S-PTAD)4
- (2S)-2-(1-adamantyl)-2-(1,3-dioxoisoindol-2-yl)acetic acid,rhodium
- Tetrakis[(S)-2-(1-adamantyl)-2-(1,3-dioxo-2-isoindolinyl)acetic Acid] Dirhodium(II)
- CAS:
- 909389-99-7
- MF:
- C80H80N4O16Rh2
- MW:
- 1559.34
- Product Categories:
-
- organometallic complex
- Rh
- Mol File:
- 909389-99-7.mol
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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Chemical Properties
- Melting point:
- >300°C
- alpha
- +39.1 (c 0.2, CHCl3)
- form
- Powder
- color
- green
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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Usage And Synthesis
Reaction
- Enantioselective reactions of carbenoids and olefins.
- Enantioselective C–H insertion reactions of carbenoids.
- Enantioselective oxygen transfer from diazosulfonylamidines.
Uses
This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4Supplier
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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4(909389-99-7)Related Product Information
- ADAMANTAN-1-YL-AMINO-ACETIC ACID
- BZL-ILE-OH
- Rhodium(II) octanoate dimer
- PHT-VAL-OH
- (-)-N-FORMYL-L-TERT-LEUCINE
- RHODIUM(II) HEXANOATE DIMER
- N-Acetyl-DL-cyclohexylglycine
- PHT-ILE-OH
- (S)-ACETYLAMINO-CYCLOHEXYL-ACETIC ACID
- 3-methyl-2-(1-oxo-1,3-dihydro-2H-isoindol-2-yl)pentanoic acid
- Rhodium acetate
- 1-Adamantaneacetic acid
- Rhodium(II) acetate dimer
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4