ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Aromatic ketones > 5-Bromo-2-hydroxyacetophenone
5-Bromo-2-hydroxyacetophenone
5-Bromo-2-hydroxyacetophenone Basic information
- Product Name:
- 5-Bromo-2-hydroxyacetophenone
- Synonyms:
-
- 1-(5-BROMO-2-HYDROXYPHENYL)ETHANONE
- 2-ACETYL-4-BROMOPHENOL
- 5'-BROMO-2'-HYDROXYACETOPHENONE
- 5-BROMO-2-HYDROXYACETOPHENONE
- 1-(5-bromo-2-hydroxyphenyl)-ethanon
- AKOS BBS-00006622
- 2’-hydroxy-5’-bromoacetophenone
- 5’-bromo-2’-hydroxy-acetophenon
- CAS:
- 1450-75-5
- MF:
- C8H7BrO2
- MW:
- 215.04
- EINECS:
- 604-457-2
- Product Categories:
-
- Building Blocks
- C7 to C8
- C7 to C8
- Carbonyl Compounds
- Chemical Synthesis
- Organic Building Blocks
- Aromatic Acetophenones & Derivatives (substituted)
- Adehydes, Acetals & Ketones
- Bromine Compounds
- Phenols
- Carbonyl Compounds
- Ketones
- Mol File:
- 1450-75-5.mol
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5-Bromo-2-hydroxyacetophenone Chemical Properties
- Melting point:
- 58-61 °C(lit.)
- Boiling point:
- 135-143 °C(Press: 16 Torr)
- Density
- 1.586±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Soluble in Chloroform
- pka
- 9.59±0.18(Predicted)
- form
- Solid
- color
- White to pale yellow
- LogP
- 3.110 (est)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- RTECS
- KM5556350
- HazardClass
- IRRITANT
- HS Code
- 29147000
- Toxicity
- mouse,LD50,intraperitoneal,> 1gm/kg (1000mg/kg),Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. Vol. 20, Pg. 480, 1981.
MSDS
- Language:English Provider:SigmaAldrich
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5-Bromo-2-hydroxyacetophenone Usage And Synthesis
Chemical Properties
White to pale yellow crystalline powder
Uses
5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.
Preparation
Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%).
5-Bromo-2-hydroxyacetophenoneSupplier
Shanghai Harvest Chemical Industrial Co., Ltd. Gold
- Tel
- 21-31038972 15721252604
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Jiangsu Hi-Pure Technology New Materials Co. Ltd. Gold
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- sales@hi-pure.cn
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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- 4006608290; 18621169109
- market03@meryer.com
INTATRADE GmbH
- Tel
- +49 3493/605464
- sales@intatrade.de
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5-Bromo-2-hydroxyacetophenone(1450-75-5)Related Product Information
- 5-Bromo-2-hydroxyphenylacetic acid
- 3',5'-Dibromo-2'-hydroxyacetophenone
- 5-BROMO-2-HYDROXYBENZOPHENONE
- 5-Bromo-2-hydroxyacetophenone
- 6-BROMOCHROMONE
- bis(5-bromo-2-hydroxyphenyl)ethanedione
- 6-BROMO-3-FORMYLCHROMONE
- 6-Bromo-2,3-dihydro-4H-chromen-4-one
- 3'-BROMO-5'-CHLORO-2'-HYDROXYACETOPHENONE
- 4-BROMO-2-HYDROXYACETOPHENONE,4-Bromo-2-hydroxyacetophenone ,97%
- OMEGA-BROMO-4-HYDROXYACETOPHENONE,w-Bromo-4-Hydroxyacetophenone
- 2'-BROMO-4'-HYDROXYACETOPHENONE,2-BROMO-4'-HYDROXYACETOPHENONE,ALPHA-BROMO-4-HYDROXYACETOPHENONE,α-Bromo-4-hydroxyacetophenone,2-Bromo-4-Hydroxyacetophenone98%
- 2-Bromo-2′-hydroxyacetophenone
- 4'-BROMO-2-HYDROXYACETOPHENONE
- 1-(5-BROMO-2-HYDROXY-4-METHOXYPHENYL)-ETHANONE
- 6,8-DIBROMO-3-FORMYLCHROMONE, 99%
- 4-Bromo-6,7-dimethoxyindanone
- 2-AMINO-7-BROMO-5-OXO-5H-(1)BENZOPYRANO&