(Bromomethyl)cyclopropane Chemical Properties

Melting point:

87-90 °C

Boiling point:

105-107 °C(lit.)

Density 

1.392 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.457(lit.)

Flash point:

107 °F

storage temp. 

Inert atmosphere,2-8°C

solubility 

Chloroform (Slightly), Methanol (Slightly)

form 

Liquid

Specific Gravity

1.392

color 

Clear colorless to slightly colored

Water Solubility 

Not miscible in water.

BRN 

605296

Stability:

Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.

InChIKey

AEILLAXRDHDKDY-UHFFFAOYSA-N

CAS DataBase Reference

7051-34-5(CAS DataBase Reference)

NIST Chemistry Reference

Cyclopropane, (bromomethyl)-(7051-34-5)

Safety Information

Hazard Codes 

Xi,F,Xn

Risk Statements 

10-36/37/38-22

Safety Statements 

23-24/25-37/39-26-16-36/37/39

RIDADR 

UN 1993 3/PG 3

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

3

PackingGroup 

III

HS Code 

29035990

MSDS

• Language:English Provider:1-(Bromomethyl)cyclopropane
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

(Bromomethyl)cyclopropane Usage And Synthesis

Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description

(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Chemical Properties

Colorless to yellow liquid

Uses

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

(Bromomethyl)cyclopropane(7051-34-5)Related Product Information

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