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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)-

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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)- Basic information

Product Name:
C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)-
Synonyms:
  • C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)-
  • (10bR)-1a,2,5,6,11,12-Hexahydro-8,9,12β-trimethoxy-4H-oxireno[3,3a]indolo[7a,1-a][2]benzazepine
  • 1,2-Didehydro-6ξ,7ξ-epoxy-3β,15,16-trimethoxy-C-homoerythrinan
  • Alkaloid PC-VII
  • 3-Epiwilsonine
  • 4H-Oxireno[3,3a]indolo[7a,1-a][2]benzazepine,1a,2,5,6,11,12-hexahydro-8,9,12-trimethoxy-, [1aR-(1aa,10bR*,12a)]- (9CI)
  • 4H-Oxireno[3,3a]indolo[7a,1-a][2]benzazepine, 1a,2,5,6,11,12-hexahydro-8,9,12-trimethoxy-, (1aR,10bR,12R,14aS)-
  • (1aR,10bR,12R,14aS)-8,9,12-Trimethoxy-1a,2,5,6,11,12-hexahydro-4H-oxireno[3,3a]indolo[7a,1-a][2]benzazepine
CAS:
39024-15-2
MF:
C20H25NO4
MW:
343.42
Mol File:
39024-15-2.mol
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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)- Chemical Properties

Melting point:
103-4°C
Boiling point:
474.8±45.0 °C(Predicted)
Density 
1.27±0.1 g/cm3(Predicted)
solubility 
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form 
Oil
pka
6.07±0.40(Predicted)
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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3beta, 6xi)- Usage And Synthesis

Description

A further alkaloid present in Cephalotaxus wilsoniana Hayata, this base forms colourless crystals from Et20 and is dextrorotatory with [α]D + 60.7° (c 0.85, CHC13) or + 75.8° (c 0.52, EtOH).

References

Powell et al., Phytochem., 11,3317 (1972)

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