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4-Biphenylboronic acid

Basic information Safety Supplier Related

4-Biphenylboronic acid Basic information

Product Name:
4-Biphenylboronic acid
Synonyms:
  • RARECHEM AH PB 0261
  • (1,1'-BIPHENYL-4-YL)BORONIC ACID
  • AKOS BRN-0030
  • 4-PHENYLBENZENEBORONIC ACID
  • 4-PHENYLPHENYLBORONIC ACID
  • 4-BIPHENYLBORONIC ACID
  • 4-BIPHENYLYLBORONIC ACID
  • BIPHENYL-4-BORONIC ACID
CAS:
5122-94-1
MF:
C12H11BO2
MW:
198.03
EINECS:
675-084-0
Product Categories:
  • Boronic acid
  • Organoborons
  • B (Classes of Boron Compounds)
  • Aryl
  • Boronic Acids
  • Boronic Acids and Derivatives
  • Boron Compounds
  • blocks
  • BoronicAcids
  • Substituted Boronic Acids
  • Boronic Acids
  • Boronic acid series
Mol File:
5122-94-1.mol
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4-Biphenylboronic acid Chemical Properties

Melting point:
232-245 °C (lit.)
Boiling point:
385.5±35.0 °C(Predicted)
Density 
1.18±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Acetone,Methanol
pka
8.61±0.10(Predicted)
form 
Powder
color 
White
Water Solubility 
Insoluble in water.
BRN 
2937410
CAS DataBase Reference
5122-94-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-37/39-36-24/25
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29310095

MSDS

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4-Biphenylboronic acid Usage And Synthesis

Chemical Properties

Solid

Uses

suzuki reaction: Suzuki coupling of 2-(4-bromophenyl)thiophene with phenylboronic acid and 4-biphenylboronic acid are used for the preparation of 4-(2-thieny)biphenyl and 4-(2-thienyl)-1,1':4,1''-biphenyl respectively. Coupling of two equivalents of 4-(2-thienyl)phenylboronic acid with 1,4-diiodobenzene gives 4,4''-bis(2-thienyl)-1,1':4,1''-terphenyl and with 2,5-diiodothiophene, 2,5-bis[4-(2-thienyl)-phenyl]-thiophene is obtained.

Uses

Used in Suzuki reactions and as intermediates of liquid crystals.

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