Basic information Reaction Safety Supplier Related

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

Basic information Reaction Safety Supplier Related

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information

Product Name:
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:
  • (1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl
  • Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
  • N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.
  • N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]
  • TROST LIGAND
  • (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
  • (1R,2R)-(+)-1,2-TROST LIGAND
  • "N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand"
CAS:
138517-61-0
MF:
C44H40N2O2P2
MW:
690.75
Product Categories:
  • Chiral Nitrogen
  • DACH&Trost Series
Mol File:
138517-61-0.mol
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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties

Melting point:
134-136°C
alpha 
+130° (c 1.0, methanol)
Boiling point:
817.0±65.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
13.35±0.40(Predicted)
color 
white to off-white
optical activity
[α]20/D +131°, c = 1 in methanol
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)Supplier

Daicel Chiral Technologies (China)CO.,LTD Gold
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