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4-Nitrophenylboronic acid pinacol ester

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4-Nitrophenylboronic acid pinacol ester Basic information

Product Name:
4-Nitrophenylboronic acid pinacol ester
Synonyms:
  • 4-NITROPHENYLBORONIC ACID PINACOL ESTER
  • 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)NITROBENZENE
  • 4-Nitrobenzeneboronic acid, pinacol ester
  • 4,4,5,5-tetramethyl-2-(4-nitrophenyl)-1,3,2-dioxaborolane
  • 2-(4-Nitrophenyl)-4,4,5,5,-tetramethyl-1,3,2-dioxaborolane, 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
  • 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-nitrophenyl)-
  • 4-Nitrophenylboronic acid pinacol ester 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
  • -Nitrophenylboronic acid pinacol ester
CAS:
171364-83-3
MF:
C12H16BNO4
MW:
249.07
Product Categories:
  • Aryl Boronate Esters
  • Boronate Esters
  • Aryl
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • blocks
  • BoronicAcids
  • NitroCompounds
  • Boronic ester
  • Organoborons
  • Pyrimidines
Mol File:
171364-83-3.mol
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4-Nitrophenylboronic acid pinacol ester Chemical Properties

Melting point:
112-116 °C (lit.)
Boiling point:
357.5±25.0 °C(Predicted)
Density 
1.14±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder or crystals
color 
White to Orange to Green
Water Solubility 
Slightly soluble in water.
CAS DataBase Reference
171364-83-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
Hazard Note 
Harmful/Store Cold
HazardClass 
IRRITANT
HS Code 
29333990

MSDS

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4-Nitrophenylboronic acid pinacol ester Usage And Synthesis

Chemical Properties

White solid

Uses

Reactant involved in: • ;Synthesis of aryl azides 1• ;Arylation of allylic chlorides2• ;Syntehsis of RNA conjugates3• ;Alkoxycarbonylation4• ;Synthesis of mTOR and PI3K inhibitors as antitumor agents5• ;Electrooxidative synthesis of biaryls6

Uses

suzuki reaction

Uses

4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024

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