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Tris(4-bromophenyl)amine

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Tris(4-bromophenyl)amine Basic information

Product Name:
Tris(4-bromophenyl)amine
Synonyms:
  • TRIS(4-BROMOPHENYL)AMINE
  • 4,4',4''-Nitrilotris(1-bromobenzene)
  • N,N-Bis(4-bromophenyl)-4-bromoaniline
  • TRIS(4-BROMOPHENYL)AMIN
  • 4,4',4"-Tribromotriphenylamine
  • TRI(4-BROMOPHENYL)AMINE
  • Tris(4-bromophenyl)amine (purified by sublimation)
  • 4-broManyl-N,N-bis(4-broMophenyl)aniline
CAS:
4316-58-9
MF:
C18H12Br3N
MW:
482.01
EINECS:
628-703-3
Product Categories:
  • Electronic Chemicals
  • Acid Anhydrides, etc. (Reagents for Conducting Polymer Research)
  • Fluorenes, etc. (reagent for high-performance polymer research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • Reagents for Conducting Polymer Research
  • White to light yellow crystalline powder
  • White powder
  • Amines
  • C11 to C38
  • Nitrogen Compounds
  • OLED
Mol File:
4316-58-9.mol
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Tris(4-bromophenyl)amine Chemical Properties

Melting point:
141-143 °C (lit.)
Boiling point:
514.9±45.0 °C(Predicted)
Density 
1.790±0.06 g/cm3(Predicted)
Flash point:
100°C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in toluene.
pka
-4.91±0.50(Predicted)
form 
powder to crystal
color 
White to Almost white
Stability:
Stable. Incompatible with strong oxidizing agents.
InChI
InChI=1S/C18H12Br3N/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey
ZRXVCYGHAUGABY-UHFFFAOYSA-N
SMILES
C1(N(C2=CC=C(Br)C=C2)C2=CC=C(Br)C=C2)=CC=C(Br)C=C1
CAS DataBase Reference
4316-58-9(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29214990

MSDS

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Tris(4-bromophenyl)amine Usage And Synthesis

Chemical Properties

Tris(4-bromophenyl)amine typically appears as a white crystalline powder at room temperature and pressure. This compound is chemically active and reacts with oxidants and acid mixtures.

Uses

Tris(4-bromophenyl)amine was used in the synthesis of porous luminescent covalent--organic polymers (COPs)

Application

Tri(4-bromophenyl)amine is a key raw material for the synthesis of a novel three-branched triphenylamine organoboron complex (TPAB). TPAB can be successfully synthesized through Suzuki coupling, condensation, and coordination reactions with 4-aminophenylboronic acid pinacol ester, 4-diethylaminosalicylaldehyde, and boron trifluoride etherate.

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