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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organonickel >  BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II)

BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II)

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BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II) Basic information

Product Name:
BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II)
Synonyms:
  • BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II)
  • BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANE-DIONATO)NICKEL(III)
  • ni(tmhd)2
  • [Nickel(II) thd]
  • NICKEL (2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE)
  • NICKEL TMHD
  • NICKEL (II) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE
  • NICKEL(II) BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE)
CAS:
14481-08-4
MF:
C22H38NiO4
MW:
425.23
Product Categories:
  • Ni
Mol File:
14481-08-4.mol
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BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II) Chemical Properties

Melting point:
219-223 °C(lit.)
Boiling point:
90-110°C/0.1mm
Flash point:
90-110°C/0.1mm subl.
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
purple
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:
hygroscopic
InChI
1S/2C11H20O2.Ni/c2*1-10(2,3)8(12)7-9(13)11(4,5)6;/h2*7,12H,1-6H3;/q;;+2/p-2/b2*8-7+;
InChIKey
PIIJAZNTPALBJL-ORWWTJHYSA-L
SMILES
CC(C)(C)C(=O)\C=C(\O[Ni]O\C(=C\C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
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Safety Information

Hazard Codes 
T,Xi
Risk Statements 
45-20/21/22
Safety Statements 
53-36/37-45
WGK Germany 
3
HS Code 
2914199090
Storage Class
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications
Acute Tox. 4 Oral
Carc. 1B

MSDS

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BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II) Usage And Synthesis

Uses

NMR shift reagent, nickel oxide precursor

reaction suitability

core: nickel

BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)NICKEL(II)Supplier

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