[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Basic information
- Product Name:
- [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
- Synonyms:
-
- [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
- Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold
- Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold
- CAS:
- 915299-24-0
- MF:
- C42H64AuClO3P
- MW:
- 880.36
- Product Categories:
-
- Au
- Mol File:
- 915299-24-0.mol
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[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Chemical Properties
- Melting point:
- 200-202 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- powder
- InChIKey
- GCWCLHMEYZKZRO-UHFFFAOYSA-M
- SMILES
- Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
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[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Usage And Synthesis
Uses
Gold Catalysts — 21st Century ′Gold Rush′
- Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes
Catalyst for:
- [4C+2C] cycloadditions
- Cis-selective single-cleavagte skeletal cycloisomerization
- Diastereoselective Au-catalyzed intermolecular cyclopropanation
- Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
- Addition reactions
reaction suitability
core: gold
reagent type: catalyst
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chlorideSupplier
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