MPC Chemical Properties

Boiling point:

125 °C(Press: 630 Torr)

Density 

0.976±0.06 g/cm3(Predicted)

storage temp. 

2-8°C

Appearance

Colorless to light yellow Liquid

MPC Usage And Synthesis

Synthesis

The general procedure for the synthesis of 2-aminobenzimidazole, propyl carbonate and methylpropyl carbonate from n-propanol and compounds (CAS:162976-69-4) is as follows: amide-containing compounds having a (benzo)imidazole-2-yl group can be subjected to catalytic directional cleavage reactions with alcohol nucleophilic reagents in the presence of a metal catalyst. Specific embodiments are described in Scheme ES: using 10.0 mol% Zn(OAc)2-2H2O as a catalyst, 1.0 equivalent of ACDG-NH-C(O)-R3 (21d), and 30.0 equivalents of propanol (under sealed conditions) for a reaction time of 24 hr; wherein R is a 1H-benzo[d]imidazol-2-yl group, and R3 is an OMe. Reaction products The yields were determined by NMR analysis using TMB as an internal standard: 0% for unreacted 21d, 61% for 2-aminobenzimidazole (20d), 40% for methylpropyl carbonate (14c) and 22% for dipropyl carbonate (14d).

References

[1] Patent: WO2017/46133, 2017, A1. Location in patent: Page/Page column 58; 59

MPC(56525-42-9)Related Product Information

• Isopropyl palmitate
• Propyl gallate
• Lithium carbonate
• Dimethyl carbonate
• Ethylene carbonate
• Propyl acetate
• Sodium carbonate
• Ethyl methyl carbonate
• Dipropyl carbonate
• Isopropyl acetate
• LANTHANUM CARBONATE
• HOLMIUM CARBONATE
• Guanidine carbonate
• Strontium carbonate
• SODIUM CARBONATE, MONOHYDRATE
• Diisopropyl carbonate
• Calcium carbonate
• Carbonic acid dihexyl ester