1,2,3,4,5-Pentamethylcyclopentadiene
1,2,3,4,5-Pentamethylcyclopentadiene Basic information
- Product Name:
- 1,2,3,4,5-Pentamethylcyclopentadiene
- Synonyms:
-
- Cyclopentadiene, 1,2,3,4,5-pentamethyl-
- 1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE
- 1,2,3,4,5-pentamethyl-1,3-cyclopentadiene
- 1,2,3,4,5-Pentamethylcyclopentadiene, tech
- 1,2,3,5,5-pentamethylcyclopenta-1,3-diene
- PENTAMETHYLCYCLOPENTADIENE
- 1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE, 95 %
- PENTAMETHYLCYCLOPENTADIENE 98+%
- CAS:
- 4045-44-7
- MF:
- C10H16
- MW:
- 136.23
- EINECS:
- 223-743-4
- Product Categories:
-
- organic compound
- In organic synthesis, high-energy rocket fuel, plasticizer, surface coating, curing agent, polymer synthetic materials
- Alkenes
- Cyclic
- Organic Building Blocks
- Mol File:
- 4045-44-7.mol
1,2,3,4,5-Pentamethylcyclopentadiene Chemical Properties
- Boiling point:
- 58 °C13 mm Hg(lit.)
- Density
- 0.87 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.474(lit.)
- Flash point:
- 112 °F
- storage temp.
- Store below +30°C.
- form
- Liquid
- color
- Clear colorless to yellow-orange, may darken on storage
- Specific Gravity
- 0.87
- Water Solubility
- Miscible with methanol. dichloromethane and ethyl acetate. Slightly miscible with water.
- Sensitive
- Light Sensitive
- BRN
- 1849832
- Stability:
- store cold
- CAS DataBase Reference
- 4045-44-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-(4045-44-7)
MSDS
- Language:English Provider:1,2,3,4,5-Pentamethyl-1,3-cyclopentadiene
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
1,2,3,4,5-Pentamethylcyclopentadiene Usage And Synthesis
Chemical Properties
clear colorless to yellowish liquid
Uses
1,2,3,4,5-Pentamethylcyclopentadiene serves as a precursor to the ligand 1,2,3,4,5-pentamethylcyclopentadienyl. It is used as a growth modifier chemical, during metal organic chemical vapor deposition of iron from iron pentacarbonyl. It is used as a ligand in "one-pot" iridium-catalyzed transformation of alcohols to amides. Further, it acts as an electron mediator in the regeneration process of nicotinamide adenine dinucleotide. In addition to this, it undergoes radical cation catalyzed cycloaddition reaction with allenes to get Diels-Alder product.
General Description
Mechanism of the Diels-Alder reaction of paramagneticendohedral metallofullerene and 1,2,3,4,5-pentamethylcyclopentadiene has been studied. Three-step large-scale preparation of 1,2,3,4,5-pentamethylcyclopentadiene has been reported. Reaction of 1,2,3,4,5-pentamethylcyclopentadiene (HCp*) with actinide ions in gas phase has been investigated by laser ablation mass spectrometry. It undergoes radical cation catalyzed cycloaddition with electron rich allenes to form Diels-Alder product.
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1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)Related Product Information
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