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Diethyl (2-oxopropyl)phosphonate

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Diethyl (2-oxopropyl)phosphonate Basic information

Product Name:
Diethyl (2-oxopropyl)phosphonate
Synonyms:
  • Diethyl(2-oxopropyl)phosphonate, 97 %
  • DIETHYL ACETYLPHOSPHONATE
  • DIETHYL(2-OXOPROPYL)PHOSPHONATE
  • AURORA KA-1476
  • (2-Oxo-propyl)-phosphonicaciddiethylester
  • ACETYLPHOSPHONIC ACID DIETHYL ESTER
  • (2-Oxopropyl)phosphonic Acid Diethyl Ester Diethyl Acetonylphosphonate Acetonylphosphonic Acid Diethyl Ester
  • Diethyl acetylmethylphosphonate, 97%
CAS:
1067-71-6
MF:
C7H15O4P
MW:
194.17
EINECS:
682-094-9
Product Categories:
  • Horner-Wadsworth-Emmons Reagents
  • C-C Bond Formation
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination
Mol File:
1067-71-6.mol
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Diethyl (2-oxopropyl)phosphonate Chemical Properties

Boiling point:
126 °C9 mm Hg(lit.)
Density 
1.01 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.433(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Miscible with tetrahydrofuran, ether, dichloromethane and chloroform.
form 
Liquid
color 
Clear colorless to light yellow
CAS DataBase Reference
1067-71-6(CAS DataBase Reference)
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Safety Information

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29319090

MSDS

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Diethyl (2-oxopropyl)phosphonate Usage And Synthesis

Chemical Properties

CLEAR COLORLESS TO LIGHT YELLOW LIQUID

Uses

Diethyl (2-Oxopropyl)phosphonate, is used in the preparation of enantipure acetoxyalkanephosphonates thru dynamic enzymic kinetic resolution alpha- and beta-hydroxalkanephosphonates.

Synthesis Reference(s)

Tetrahedron, 34, p. 649, 1978 DOI: 10.1016/0040-4020(78)88099-5
Tetrahedron Letters, 17, p. 2829, 1976 DOI: 10.1016/S0040-4039(01)85513-1

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