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2-NAPHTHYLAMINE-8-SULFONIC ACID

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2-NAPHTHYLAMINE-8-SULFONIC ACID Basic information

Product Name:
2-NAPHTHYLAMINE-8-SULFONIC ACID
Synonyms:
  • 7-amino-1-naphthalenesulfonicaci
  • 7-AMINO-1-NAPHTHALENESULFONIC ACID
  • AMINOCROCEINIC ACID
  • 2-NAPHTHYLAMINE-8-SULFONIC ACID
  • 7-azanylnaphthalene-1-sulfonic acid
  • 7-Naphthylamine-1-sulfonic acid
  • BADISCHE ACID
  • BADEN ACID
CAS:
86-60-2
MF:
C10H9NO3S
MW:
223.25
EINECS:
201-685-0
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
86-60-2.mol
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2-NAPHTHYLAMINE-8-SULFONIC ACID Chemical Properties

Boiling point:
220°C (rough estimate)
Density 
1.3588 (rough estimate)
refractive index 
1.6500 (estimate)
pka
-0.34±0.40(Predicted)
Water Solubility 
0.6g/L(20 ºC)
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Safety Information

RIDADR 
1759
HazardClass 
8
PackingGroup 
III
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2-NAPHTHYLAMINE-8-SULFONIC ACID Usage And Synthesis

Description

2-Aminonaphthalene-8-sulfonic acid [86- 60-2]. (7-aminonaphthalene-1-sulfonic acid), Badische acid, C10H9NO3S, Mr 223.24, crystallizes from water as needles or prisms although only 0.5 % soluble at 100 ℃. Alkalimetal salts are quite soluble in water. Caustic fusion yields 7-amino-1-naphthol, sulfonation in the cold with 20 % oleum gives 2-aminonaphthalene-6,8-disulfonic acid, but nitration gives a mixture of products. 2-Aminonaphthalene-8-sulfonic acid reacts with diazo compounds to form diazoamino compounds rather than coupling to give azo derivatives.

Chemical Properties

Colorless needles, partially soluble in water and alkalies, slightly soluble in alcohol.

Uses

Azo dye intermediate.

Production Methods

2-Hydroxynaphthalene-8-sulfonic acid is aminated by a Bucherer reaction under conditions similar to those used for Tobias acid.

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