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TRIMETHYLENE SULFIDE

Basic information Safety Supplier Related

TRIMETHYLENE SULFIDE Basic information

Product Name:
TRIMETHYLENE SULFIDE
Synonyms:
  • THIACYCLOBUTAN
  • THIETANE
  • TRIMETHYLENE SULFIDE
  • TRIMETHYLENE SULPHIDE
  • 1,3-Epithiopropan
  • Propane, 1,3-epithio-
  • propane,1,3-epithio-
  • Thiacyclobutane
CAS:
287-27-4
MF:
C3H6S
MW:
74.14
EINECS:
206-015-0
Product Categories:
  • Building Blocks
  • Chemical Synthesis
  • Dithietanes
  • Organic Building Blocks
  • Sulfides/Disulfides
  • Sulfur Compounds
  • Simple 4-Membered Ring Compounds
Mol File:
287-27-4.mol
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TRIMETHYLENE SULFIDE Chemical Properties

Melting point:
-73.24°C
Boiling point:
94-94.5 °C (lit.)
Density 
1.028 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.510(lit.)
Flash point:
27 °F
form 
liquid
Specific Gravity
1.028
color 
Colorless to Almost colorless
BRN 
102383
LogP
1.083 (est)
CAS DataBase Reference
287-27-4(CAS DataBase Reference)
EPA Substance Registry System
Thietane (287-27-4)
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
11-22
Safety Statements 
16
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
HS Code 
2934.99.9001
HazardClass 
3.1
PackingGroup 
II

MSDS

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TRIMETHYLENE SULFIDE Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS LIQUID

Definition

ChEBI: An organosulfur heterocyclic compound containing a saturated four membered ring with 3 carbon atom and 1 sulfur atom.

Purification Methods

Purify thietane by preparative gas chromatography on a dinonyl phthalate column. It has also been purified by drying over anhydrous K2CO3, and distilling through a 25cm glass helices-packed column (for 14g of thietane), then drying over CaSO4 before sealing it in a vacuum. [Haines et al. J Phys Chem 58 270 1954.] It is characterised as the dimethylsulfonium iodide m 97-98o [Bennett & Hock J Chem Soc 2496 1927]. The S-oxide has b 102o/25mm, n D 1.5075 [Tamres & Searles J Am Chem Soc 81 2100 1959]. [Beilstein 17 I 3, 17 II 12, 17 III/IV 14, 17/1 V 14.]

TRIMETHYLENE SULFIDESupplier

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