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1-Iodo-3-nitrobenzene

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1-Iodo-3-nitrobenzene Basic information

Product Name:
1-Iodo-3-nitrobenzene
Synonyms:
  • 1-iodo-3-nitro-benzen
  • 3-Nitroiodobenzene
  • Benzene, 1-iodo-3-nitro-
  • m-Nitrophenyliodide
  • 3-IODONITROBENZENE
  • 1-IODO-3-NITROBENZENE
  • M-IODONITROBENZENE
  • M-NITROIODOBENZENE
CAS:
645-00-1
MF:
C6H4INO2
MW:
249.01
EINECS:
211-427-9
Product Categories:
  • Benzene derivates
  • Iodine Compounds
  • Nitro Compounds
  • Nitro Compounds
  • Nitrogen Compounds
  • Organic Building Blocks
Mol File:
645-00-1.mol
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1-Iodo-3-nitrobenzene Chemical Properties

Melting point:
36-38 °C (lit.)
Boiling point:
280 °C (lit.)
Density 
1.9477
Flash point:
161 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
form 
powder to lump to clear liquid
color 
Light yellow to Yellow
Water Solubility 
insoluble
Sensitive 
Light Sensitive
BRN 
1525167
Stability:
Stable. Highly flammable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference
645-00-1(CAS DataBase Reference)
NIST Chemistry Reference
m-Iodonitrobenzene(645-00-1)
EPA Substance Registry System
m-Iodonitrobenzene (645-00-1)
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Safety Information

Hazard Codes 
Xn,F,Xi
Risk Statements 
20/21/22-36/37/38-36-33-11
Safety Statements 
26-36/37/39-45-16-36
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
4.1
HS Code 
29049090

MSDS

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1-Iodo-3-nitrobenzene Usage And Synthesis

Chemical Properties

yellow to yellow-green powder

Uses

1-Iodo-3-nitrobenzene was used in the synthesis of 5-substituted pyrrolo[3,2-b]pyridine amide and 3′-nitro-4-methylthiobiphenyl. It was used in palladium(0) catalyzed cross-coupling reaction between heteroarylzinc iodide and unsaturated iodide.

Definition

ChEBI: A C-nitro compound that is nitrobenzene bearing an iodine substituent at C-3.

General Description

Monoclinic prisms or tan solid.

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