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XantPhos-Pd-G2

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XantPhos-Pd-G2 Basic information

Product Name:
XantPhos-Pd-G2
Synonyms:
  • Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(2-amino-1,1-biphenyl-2-yl)palladium(II)
  • CHLORO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.2]
  • Xantphos Palladacycle Gen.2
  • Chloro[(4,5-bis(diphenylphosphino)-9,9-diMethylxanthene)-2-(2'-aMino-1,1'-bipheny
  • Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II),XantPhos Pd G2
  • Chloro[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%
  • Chloro[(4,5-bis(diphenylphosphino)-9,9-diMethylxanthene)-2-(2'-aMino-1,1'-biphenyl)]palladiuM(II)
  • Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct
CAS:
1375325-77-1
MF:
C51H42ClNOP2Pd
MW:
888.72
Product Categories:
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
Mol File:
1375325-77-1.mol
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XantPhos-Pd-G2 Chemical Properties

Melting point:
188-196 (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
pale yellow
InChI
InChI=1S/C39H32OP2.C12H9N.ClH.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h3-28H,1-2H3;1-6,8-9,13H;1H;/q;-2;;+2
InChIKey
WBWMRHAPSXPODD-UHFFFAOYSA-N
SMILES
P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=C2C(C3=CC=CC(P(C4C=CC=CC=4)C4C=CC=CC=4)=C3OC=12)(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
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Safety Information

WGK Germany 
3
HS Code 
2931499090
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XantPhos-Pd-G2 Usage And Synthesis

Description

XantPhos-Pd-G2 is an inhibitor of palladium-catalyzed cross-coupling reactions. It is stable, and can be used as a catalyst for the cross-coupling of a variety of activated, metalated organic compounds with alkyl halides.

Uses

XantPhos-Pd-G2 is a second generation palladium precatalyst with improved reactivity in palladium-catalyzed C-N cross-coupling reactions.

Application

XantPhos-Pd-G2 is used to synthesize various pharmaceuticals, including antihypertensive drugs and antibiotics.

XantPhos-Pd-G2Supplier

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