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4,4'-Bis(4-aminophenoxy)biphenyl

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4,4'-Bis(4-aminophenoxy)biphenyl Basic information

Product Name:
4,4'-Bis(4-aminophenoxy)biphenyl
Synonyms:
  • 4,4'-(1,1'-BIPHENYL-4,4'-DIYLDIOXY)DIANILINE
  • 4,4'-(P-BIPHENYLENEDIOXY)DIANILINE
  • 4,4-BIS(4-AMINOPHENOXY)BIPHENYL(44BAPOBP) 98%
  • 4,4'-Bis(4-aminophenoxy)biphenyl ,99%
  • 4,4'-(1,1'-Biphenyl-4,4'-diylbisoxy)bisaniline
  • 4,4'-(Biphenyl-4,4'-diylbisoxy)bis(aniline)
  • 4,4'-[(1,1'-Biphenyl-4,4'-diyl)bis(oxy)]bisaniline
  • 4,4'-[(4,4'-Biphenylylene)bisoxy]bisaniline
CAS:
13080-85-8
MF:
C24H20N2O2
MW:
368.43
EINECS:
627-298-0
Product Categories:
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
  • Biphenyl & Diphenyl ether
  • Biphenyls (for High-Performance Polymer Research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
Mol File:
13080-85-8.mol
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4,4'-Bis(4-aminophenoxy)biphenyl Chemical Properties

Melting point:
197-200 °C(lit.)
Boiling point:
571.4±50.0 °C(Predicted)
Density 
1.226±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
DMSO: 74 mg/mL (200.85 mM);;
form 
powder to crystal
pka
5.10±0.10(Predicted)
color 
White to Gray to Red
InChI
InChI=1S/C24H20N2O2/c25-19-5-13-23(14-6-19)27-21-9-1-17(2-10-21)18-3-11-22(12-4-18)28-24-15-7-20(26)8-16-24/h1-16H,25-26H2
InChIKey
HYDATEKARGDBKU-UHFFFAOYSA-N
SMILES
C1(C2=CC=C(OC3=CC=C(N)C=C3)C=C2)=CC=C(OC2=CC=C(N)C=C2)C=C1
CAS DataBase Reference
13080-85-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29222990

MSDS

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4,4'-Bis(4-aminophenoxy)biphenyl Usage And Synthesis

Description

4,4’-(1,1’-Biphenyl-4,4’-diyldioxy)dianiline is a diamine component of polyimide aerogels, super fibers, and thermoplastic shape memory polymers.1,2,3WARNING This product is not for human or veterinary use.

Chemical Properties

White powder

Uses

4,4'-Bis(4-aminophenoxy)biphenyl, it is a kind of material type chemical intermediate product of excellent property, it is one of synthesis of polyimides important source material, also can be used for fire resistant polyimide carbon fibre reinforced composite, or the important source material of synthesis polymaleimide.

Preparation

The preparation method includes the steps that with biphenol and p-nitrchlorobenzene as raw materials, a salt forming agent and a strong-polarity aprotic solvent are added and mixed under nitrogen protection, a reflux reaction is performed for 3-5 h at 130-140°C, filtration is performed at the high temperature, filtration residues are removed, deionized water is dropwise added into filtrate, and cooling, filtration, washing and drying are performed to obtain 4,4'-Bis(4-aminophenoxy)biphenyl.

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