Basic information Safety Supplier Related

t-Boc-N-amido-PEG8-acid

Basic information Safety Supplier Related

t-Boc-N-amido-PEG8-acid Basic information

Product Name:
t-Boc-N-amido-PEG8-acid
Synonyms:
  • 5,8,11,14,17,20,23,26-Octaoxa-2-azanonacosanedioic acid, 1-(1,1-dimethylethyl) ester
  • t-Boc-N-amido-PEG8-acid
  • t-Boc-N-amido-PEG9-acid
  • Boc-N-amido-PEG8-acid
  • T-BOC-NH-AMIDO-PEG8-COOH
  • t-Boc-N-amido-PEG8-COOH,Boc-N-amido-PEG8-acid
  • Boc-NH-PEG8-acid
  • 2,2-Dimethyl-4-oxo-3,8,11,14,17,20,23,26,29-nonaoxa-5-azadotriacontan-32-oic acid
CAS:
1334169-93-5
MF:
C24H47NO12
MW:
541.63
Product Categories:
  • peg
Mol File:
1334169-93-5.mol
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t-Boc-N-amido-PEG8-acid Chemical Properties

Boiling point:
627.6±55.0 °C(Predicted)
Density 
1.122±0.06 g/cm3(Predicted)
storage temp. 
2-8°C, sealed storage, away from moisture
solubility 
Soluble in Water, DMSO, DCM, DMF
pka
4.28±0.10(Predicted)
form 
Liquid
color 
Colorless to light yellow
InChI
InChI=1S/C24H47NO12/c1-24(2,3)37-23(28)25-5-7-30-9-11-32-13-15-34-17-19-36-21-20-35-18-16-33-14-12-31-10-8-29-6-4-22(26)27/h4-21H2,1-3H3,(H,25,28)(H,26,27)
InChIKey
XYVCCDSFTREKQJ-UHFFFAOYSA-N
SMILES
C(OC(C)(C)C)(=O)NCCOCCOCCOCCOCCOCCOCCOCCOCCC(O)=O
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Safety Information

HS Code 
2942000090
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t-Boc-N-amido-PEG8-acid Usage And Synthesis

Description

t-Boc-N-amido-PEG8-acid is a PEG linker containing a terminal carboxylic acid and Boc-protected amino group. The hydrophilic PEG spacer increases solubility in aqueous media. The terminal carboxylic acid can react with primary amine groups in the presence of activators (e.g. EDC, or HATU) to form a stable amide bond. The Boc group can be deprotected under mild acidic conditions to form the free amine.

Uses

Boc-NH-PEG8-CH2CH2COOH is a PEG-based PROTAC linker that can be used in the synthesis of PROTACs[1].

IC 50

PEGs; Alkyl/ether

References

[1] An S, et al. Small-molecule PROTACs: An emerging and promising approach for the development of targeted therapy drugs. EBioMedicine. 2018 Oct;36:553-562 DOI:10.1016/j.ebiom.2018.09.005

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