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4-Bromobenzyl bromide

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4-Bromobenzyl bromide Basic information

Product Name:
4-Bromobenzyl bromide
Synonyms:
  • A,P-DIBROMOTOLUENE
  • ,4-Dibromotoluene
  • 1-bromo-4-(bromomethyl)-benzen
  • 1-Bromo-4-(bromomethyl)benzene
  • p,-Dibromotoluene
  • AKOS BBS-00004014
  • ALPHA,P-DIBROMOTOLUENE
  • ALPHA,4-DIBROMOTOLUENE
CAS:
589-15-1
MF:
C7H6Br2
MW:
249.93
EINECS:
209-636-5
Product Categories:
  • alkyl bromide
  • C7
  • Benzyl
  • Chemical Synthesis
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • Aromatic Halides (substituted)
  • Methyl Halides
  • Phenyls & Phenyl-Het
  • Miscellaneous
  • Methyl Halides
  • Phenyls & Phenyl-Het
  • Aryl
  • Building Blocks
  • bc0001
Mol File:
589-15-1.mol
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4-Bromobenzyl bromide Chemical Properties

Melting point:
62-64 °C(lit.)
Boiling point:
115-124 °C (12 mmHg)
Density 
1.8246 (rough estimate)
refractive index 
1.6066 (estimate)
Flash point:
115-124°C/12mm
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
form 
Coarse Crystalline Solid or Solid Melt
color 
White to tan
Water Solubility 
MAY DECOMPOSE
Sensitive 
Lachrymatory
Merck 
14,1409
BRN 
606498
CAS DataBase Reference
589-15-1(CAS DataBase Reference)
EPA Substance Registry System
Benzene, 1-bromo-4-(bromomethyl)- (589-15-1)
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Safety Information

Hazard Codes 
C
Risk Statements 
34-42/43
Safety Statements 
22-26-36/37/39-45-25
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
F 
19
Hazard Note 
Corrosive/Lachrymatory
TSCA 
T
HazardClass 
8
PackingGroup 
III
HS Code 
29036990

MSDS

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4-Bromobenzyl bromide Usage And Synthesis

Chemical Properties

White solid

Uses

4-Bromobenzyl bromide is used to prepare a 20-member aminomethyl-substituted biaryl library via sequential N-alkylation of various amines.

Uses

Identification of aromatic carboxylic acids.

Synthesis Reference(s)

Synthetic Communications, 11, p. 669, 1981 DOI: 10.1080/00397918108063642

Purification Methods

Crystallise the bromide from EtOH. [Beilstein 5 IV 836.] LACHRYMATORY.

4-Bromobenzyl bromide Preparation Products And Raw materials

Raw materials

Potassium bromide4-Bromotoluene

Preparation Products

1-(4-BROMOBENZYL)PIPERAZINE

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