Basic information Safety Supplier Related

TRANS-4-METHYL-BETA-NITROSTYRENE

Basic information Safety Supplier Related

TRANS-4-METHYL-BETA-NITROSTYRENE Basic information

Product Name:
TRANS-4-METHYL-BETA-NITROSTYRENE
Synonyms:
  • trans-4-methyl-á-nitrostyrene
  • trans-4-methyl-β-nitrostyrene
  • 1-(4-METHYLPHENYL)-2-NITROETHENE
  • 1-(4-METHYLPHENYL)-2-NITROETHYLENE
  • 1-METHYL-4-(2-NITROVINYL)BENZENE
  • 1-(P-TOLYL)-2-NITROETHYLENE
  • 1-(4-Methylphenyl)-2-nitroethylene~1-(p-Tolyl)-2-nitroethylene
  • TRANS-4-METHYL-BETA-NITROSTYRENE
CAS:
5153-68-4
MF:
C9H9NO2
MW:
163.17
Product Categories:
  • Acyclic
  • Alkenes
  • Organic Building Blocks
Mol File:
5153-68-4.mol
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TRANS-4-METHYL-BETA-NITROSTYRENE Chemical Properties

Melting point:
102-104 °C (lit.)
Boiling point:
275.0±9.0 °C(Predicted)
Density 
1.141±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
Water Solubility 
Sparingly Soluble in water (0.070 g/L) (25°C).
BRN 
1864209
CAS DataBase Reference
5153-68-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3

MSDS

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TRANS-4-METHYL-BETA-NITROSTYRENE Usage And Synthesis

Uses

trans-4-Methyl-β-nitrostyrene may be used as a reagent in the synthesis of N-benzylpyrrolomorphinans. It is also used as an organic intermediate for pharmaceutical.

General Description

trans-4-Methyl-β-nitrostyrene ((E)-1-methyl-4-(2-nitrovinyl)benzene) is a nitrolefin. Its asymmetric Michael addition with benzaldehyde in the presence of silylated pyrrolidine catalyst has been reported. Its hydrogenation in the presence of Pd(II) complexes of (Z)-2-((quinolin-3-ylimino)methyl)phenol as catalyst has been studied.

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