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ChemicalBook >  Product Catalog >  Organic Chemistry >  Amides >  Acyclic polyamines and their derivatives >  N,N,N',N'-Tetramethyl-1,6-hexanediamine

N,N,N',N'-Tetramethyl-1,6-hexanediamine

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N,N,N',N'-Tetramethyl-1,6-hexanediamine Basic information

Product Name:
N,N,N',N'-Tetramethyl-1,6-hexanediamine
Synonyms:
  • u1000(amine)
  • LUPRAGEN(R) N 500
  • N,N,N',N'-TETRAMETHYL-1,3-DIAMINOHEXANE
  • N,N,N′,N′-Tetramethylhexamethylendiamin
  • Tetramethylhexamethylene diamine
  • 1,6-BIS(DIMETHYLAMINO)HEXANE
  • 3,3,4,4-TETRAMETHYLHEXANE
  • N,N,N',N'-TETRAMETHYL HEXAMETHYLENE DIAMINE
CAS:
111-18-2
MF:
C10H24N2
MW:
172.31
EINECS:
203-842-9
Product Categories:
  • Amine Monomers
  • Monomers
  • Miscellaneous
  • Tertiary Amines
  • bc0001
Mol File:
111-18-2.mol
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N,N,N',N'-Tetramethyl-1,6-hexanediamine Chemical Properties

Melting point:
-46 °C
Boiling point:
209-210 °C(lit.)
Density 
0.806 g/mL at 25 °C(lit.)
vapor pressure 
12.4Pa at 20℃
refractive index 
n20/D 1.4359(lit.)
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
miscible
form 
Liquid
pka
10.07±0.28(Predicted)
color 
Clear colorless to yellow
Water Solubility 
miscible
LogP
1.99 at 23℃
CAS DataBase Reference
111-18-2(CAS DataBase Reference)
NIST Chemistry Reference
(CH3)2N(CH2)6N(CH3)2(111-18-2)
EPA Substance Registry System
N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)
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Safety Information

Hazard Codes 
T
Risk Statements 
22-24-34-23/24
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3390 6.1/PG 1
WGK Germany 
1
RTECS 
MO1370000
HazardClass 
8
PackingGroup 
III
HS Code 
29212900

MSDS

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N,N,N',N'-Tetramethyl-1,6-hexanediamine Usage And Synthesis

Chemical Properties

clear colorless to yellow liquid

Uses

N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.

Preparation

N,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.

Flammability and Explosibility

Not classified

Solubility in organics

The amine is infinitely miscible with water, methanol, acetone, ether, and benzene, but insoluble in heptane. Because of its reactivity, CCl4 cannot be used as solvent. N,N,N',N'-Tetramethyl-1,6-hexanediamine (DETA) is hygroscopic and has a strong ammoniacal odor.

N,N,N',N'-Tetramethyl-1,6-hexanediamineSupplier

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