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2-Chloroanisole

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2-Chloroanisole Basic information

Product Name:
2-Chloroanisole
Synonyms:
  • 1-chloro-2-methoxy-benzen
  • 2-chloromethoxybenzene
  • 2-Chlorophenol methyl ether
  • Anisole, o-chloro-
  • Adjacent chlorobenzene Methoxy
  • 2-Chloroanisol
  • anisole,o-chloro-
  • benzene,1-chloro-2-methoxy-
CAS:
766-51-8
MF:
C7H7ClO
MW:
142.58
EINECS:
212-167-9
Product Categories:
  • Building Blocks
  • C2 to C7
  • Aromatic Ethers
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Anisole
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Chlorine Compounds
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
766-51-8.mol
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2-Chloroanisole Chemical Properties

Melting point:
-26.8°C
Boiling point:
195-196 °C (lit.)
Density 
1.123 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.545(lit.)
Flash point:
169 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear light yellow
Water Solubility 
0.49g/L(25 ºC)
BRN 
2042179
CAS DataBase Reference
766-51-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-2-methoxy-(766-51-8)
EPA Substance Registry System
o-Chloroanisole (766-51-8)
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Safety Information

Safety Statements 
24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29093090

MSDS

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2-Chloroanisole Usage And Synthesis

Chemical Properties

CLEAR LIGHT YELLOW LIQUID

Uses

2-Chloroanisole was used in headspace solid-phase microextraction method for the determination of haloanisoles in wine and spirit samples.

Synthesis Reference(s)

Journal of the American Chemical Society, 96, p. 2252, 1974 DOI: 10.1021/ja00814a045
The Journal of Organic Chemistry, 41, p. 732, 1976 DOI: 10.1021/jo00866a043

General Description

2-Chloroanisole undergoes acetylation with acetic anhydride over large pore zeolites to give 4-acetyl-2-chloroanisole.

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