1-Propanesulfonyl chloride Chemical Properties

Melting point:

-37 °C

Boiling point:

78-79 °C/15 mmHg (lit.)

Density 

1.267 g/mL at 25 °C (lit.)

vapor density 

4.9 (vs air)

refractive index 

n20/D 1.453(lit.)

Flash point:

176 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

clear liquid

color 

Colorless to Light yellow

Water Solubility 

Decomposes in hot water.

Sensitive 

Moisture Sensitive

BRN 

1747500

CAS DataBase Reference

10147-36-1(CAS DataBase Reference)

NIST Chemistry Reference

1-Propanesulfonyl chloride(10147-36-1)

EPA Substance Registry System

1-Propanesulfonyl chloride (10147-36-1)

Safety Information

Hazard Codes 

C

Risk Statements 

14-34-36-R36-R34-R14

Safety Statements 

26-36/37/39-45-S45-S36/37/39-S26

RIDADR 

UN 3265 8/PG 2

WGK Germany 

3

F 

10-19-21

TSCA 

Yes

HazardClass 

8

PackingGroup 

III

HS Code 

29049090

MSDS

• Language:English Provider:SigmaAldrich

1-Propanesulfonyl chloride Usage And Synthesis

Chemical Properties

Light yellow liquid

Uses

1-Propanesulfonyl chloride was used in synthesis of 1-alkyl-3-methylimidazolium alkanesulfonate ionic liquids.

Synthesis

2,4,6-Trichloro-[1,3,5]-triazine (TCT) was added at room temperature to a solution of propane-1-sulfonic acid in acetone dry, followed by NEt3 dropwise. The resulting mixture was irradiated to 80 °C (50 W of MW power) for 20 min in a sealed tube (10 mL pressure-rated reaction vial) in a self-tuning single-mode irradiating synthesizer. The mixture was cooled rapidly to room temperature by passing compressed air through the microwave cavity for 1 min. After cooling to room temperature, the precipitate was filtered off on Celite to afford 1-Propanesulfonyl chloride[1].

References

[1] Lidia De Luca, Giampaolo Giacomelli. “An Easy Microwave-Assisted Synthesis of Sulfonamides Directly from Sulfonic Acids.” The Journal of Organic Chemistry 73 10 (2008): 3967–3969.

1-Propanesulfonyl chloride (10147-36-1)Related Product Information

• Polyvinyl chloride
• Sodium chloride
• Potassium chloride
• Sulfuryl chloride
• Dansyl chloride
• Thionyl chloride
• 4-Nitrobenzenesulfonyl chloride
• Tosyl chloride
• Calcium chloride
• 1-Octanesulfonyl Chloride
• Ammonium chloride
• N-Acetylsulfanilyl chloride
• Choline chloride
• alpha-Toluenesulfonyl chloride
• Benzenesulfonyl chloride
• Procarbazone sodium
• Cyclopropanesulfonyl chloride
• chloro-propanesulfonyl chloride,3-CHLORO-1-PROPANESULFONYL CHLORIDE