ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (R)-DM-BINAP
(R)-DM-BINAP
(R)-DM-BINAP Basic information
- Product Name:
- (R)-DM-BINAP
- Synonyms:
-
- (R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
- (R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
- RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
- RAC-XYLYL-BINAP
- (R)-3,5-XYLYL-BINAP
- (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B
- (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP
- (R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
- CAS:
- 137219-86-4
- MF:
- C52H48P2
- MW:
- 734.89
- EINECS:
- 681-153-6
- Product Categories:
-
- BINAP Series
- Chiral Phosphine
- Mol File:
- 137219-86-4.mol
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(R)-DM-BINAP Chemical Properties
- Melting point:
- 203-206°C
- Boiling point:
- 825.3±65.0 °C(Predicted)
- alpha
- 169 º (c=1 in chloroform)
- storage temp.
- Inert atmosphere,Room Temperature
- Water Solubility
- Insoluble in water
- form
- crystal
- color
- white to pale yellow
- optical activity
- [α]20/D +169°, c = 1 in chloroform
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(R)-DM-BINAP Usage And Synthesis
Reaction
- Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
- Ligand used in the enantioselective fluorination of oxindoles.
- Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
- Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
- Asymmetric hydroboration of unsaturated imines.
Uses
(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.
Uses
(R)-DM-BINAPSupplier
LaaJoo Gold
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com
Xinxiang Runyu Material Co., Ltd. Gold
- Tel
- 166-166-37336996 15690792173
- chenxi.song@runvmat.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
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(R)-DM-BINAP(137219-86-4)Related Product Information
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
- (R)-(+)-TolBINAP
- (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
- RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
- RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]
- (R)-3,5-XYLYL-BINAP
- (S)-Ru(OAc)2(DM-BINAP)
- (S)-RuCl[(p-cymene)(DM-BINAP)]Cl
- (R)-Ru(OAc)2(DM-BINAP)
- RuCl2[(R)-DM-BINAP][(R)-DAIPEN]
- RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]
- (R)-RuCl[(p-cymene)(DM-BINAP)]Cl
- (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]