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1-ACETYL-1-CYCLOPENTENE
1-ACETYL-1-CYCLOPENTENE Basic information
- Product Name:
- 1-ACETYL-1-CYCLOPENTENE
- Synonyms:
-
- Ethanone, 1-(1-cyclopenten-1-yl)- (9CI)
- 1-ACETYL-1-CYCLOPENTENE
- 1-acetylcyclopentene
- 1-(1-Cyclopentenyl)ethanone
- 1-Acetylcyclopent-1-ene
- Methyl (1-cyclopentenyl) ketone
- 1-(cyclopent-1-en-1-yl)ethanone
- 1-Acetyl-1-cyclopentene 97%
- CAS:
- 16112-10-0
- MF:
- C7H10O
- MW:
- 110.15
- Product Categories:
-
- ACETYLGROUP
- C7 to C8
- Carbonyl Compounds
- Ketones
- Mol File:
- 16112-10-0.mol
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1-ACETYL-1-CYCLOPENTENE Chemical Properties
- Boiling point:
- 70 °C/20 mmHg (lit.)
- Density
- 0.955 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.483(lit.)
- Flash point:
- 59 °C
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1-ACETYL-1-CYCLOPENTENE Usage And Synthesis
Uses
1-Acetyl-1-cyclopentene may be used in the preparation of the following allenylcycloalkanes:
- 1-vinylidenyl-2-[4-(trimethylsilyl)-3-butynyl]-cyclopentane
- 1-vinylidenyl-2-(3-butynyl)-cyclopentane
Synthesis Reference(s)
The Journal of Organic Chemistry, 44, p. 450, 1979 DOI: 10.1021/jo01317a033
Tetrahedron Letters, 15, p. 1623, 1974
General Description
1-Acetyl-1-cyclopentene is a cyclic alkene. Its lithium enolate undergoes Brook rearrangement-mediated [3+4] annulation with 3-alkyl-3-haloacryloylsilanes to afford tricyclo[5.3.0.01,4]decenone derivatives. Asymmetric oxidative Heck reaction of 1-acetyl-1-cyclopentene in the presence of a Pd-ligand has been reported.
1-ACETYL-1-CYCLOPENTENESupplier
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