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1-ACETYL-1-CYCLOPENTENE

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1-ACETYL-1-CYCLOPENTENE Basic information

Product Name:
1-ACETYL-1-CYCLOPENTENE
Synonyms:
  • Ethanone, 1-(1-cyclopenten-1-yl)- (9CI)
  • 1-ACETYL-1-CYCLOPENTENE
  • 1-acetylcyclopentene
  • 1-(1-Cyclopentenyl)ethanone
  • 1-Acetylcyclopent-1-ene
  • Methyl (1-cyclopentenyl) ketone
  • 1-(cyclopent-1-en-1-yl)ethanone
  • 1-Acetyl-1-cyclopentene 97%
CAS:
16112-10-0
MF:
C7H10O
MW:
110.15
Product Categories:
  • ACETYLGROUP
  • C7 to C8
  • Carbonyl Compounds
  • Ketones
Mol File:
16112-10-0.mol
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1-ACETYL-1-CYCLOPENTENE Chemical Properties

Boiling point:
70 °C/20 mmHg (lit.)
Density 
0.955 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.483(lit.)
Flash point:
59 °C
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Safety Information

RIDADR 
UN 1224 3/PG 3
WGK Germany 
3
HS Code 
2914290090
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1-ACETYL-1-CYCLOPENTENE Usage And Synthesis

Uses

1-Acetyl-1-cyclopentene may be used in the preparation of the following allenylcycloalkanes:

  • 1-vinylidenyl-2-[4-(trimethylsilyl)-3-butynyl]-cyclopentane
  • 1-vinylidenyl-2-(3-butynyl)-cyclopentane

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 450, 1979 DOI: 10.1021/jo01317a033
Tetrahedron Letters, 15, p. 1623, 1974

General Description

1-Acetyl-1-cyclopentene is a cyclic alkene. Its lithium enolate undergoes Brook rearrangement-mediated [3+4] annulation with 3-alkyl-3-haloacryloylsilanes to afford tricyclo[5.3.0.01,4]decenone derivatives. Asymmetric oxidative Heck reaction of 1-acetyl-1-cyclopentene in the presence of a Pd-ligand has been reported.

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