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6-Hydroxy-2-naphthoic acid

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6-Hydroxy-2-naphthoic acid Basic information

Product Name:
6-Hydroxy-2-naphthoic acid
Synonyms:
  • 6-hydroxy-2-naphthalenecarboxylicacid
  • 6-hydroxy-2-naphthoicaci
  • 6-hydroxy-2-napthalenecarboxylicaci
  • 6-hydroxy-beta-naphthoicacid
  • 6-hydroxynaphthalene-2-carboxylicacid
  • 6-Hydroxy-2-naphtoic acid, 99%
  • 6-HYDROXY-2-NAPTHOIC ACID
  • 2-NAPHTHOL-6-CARBOXYLIC ACID
CAS:
16712-64-4
MF:
C11H8O3
MW:
188.18
EINECS:
240-759-7
Product Categories:
  • Intermediates of Dyes and Pigments
  • Naphthalene derivatives
  • Carboxylic
  • Bifunctional Compounds (Building Blocks for Liquid Crystals)
  • Building Blocks for Liquid Crystals
  • Chalcones, etc. (Building Blocks for Liquid Crystals)
  • Functional Materials
  • C11 to C12
  • Carbonyl Compounds
  • Carboxylic Acids
  • bc0001
  • john's
Mol File:
16712-64-4.mol
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6-Hydroxy-2-naphthoic acid Chemical Properties

Melting point:
240-250 °C (lit.)
Boiling point:
283.17°C (rough estimate)
Density 
1.2100 (rough estimate)
vapor pressure 
0Pa at 25℃
refractive index 
1.6400 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Insoluble in water
form 
Powder
pka
4.34±0.30(Predicted)
color 
Pale brown
Water Solubility 
99mg/L at 20℃
BRN 
2692084
LogP
2.1
CAS DataBase Reference
16712-64-4(CAS DataBase Reference)
EPA Substance Registry System
6-Hydroxy-2-naphthoic acid (16712-64-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
RTECS 
QN3722500
TSCA 
Yes
HS Code 
29181990
Toxicity
rat,LD50,oral,3080mg/kg (3080mg/kg),PERIPHERAL NERVE AND SENSATION: SENSORY CHANGE INVOLVING PERIPHERAL NERVEGASTROINTESTINAL: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,National Technical Information Service. Vol. OTS0534748,

MSDS

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6-Hydroxy-2-naphthoic acid Usage And Synthesis

Chemical Properties

pale brown powder

Uses

6-hydroxy-2-naphthoic acid is used for preparation engineering plastics, organic pigments, liquid crystal materials, medicine, particularly as a monomer of heat-resistant material.

Uses

6-Hydroxy-2-naphthoic acid may be used in the synthesis of 5-bromo-6-hydroxy-2-naphthoic acid and liquid-crystalline epoxy resins.

Definition

ChEBI: 6-Hydroxy-2-naphthoic acid is a naphthoic acid.

General Description

6-Hydroxy-2-naphthoic acid is a hydroxynaphthoic acid derivative. Whole cells of the recombinant Escherichia coli strain expressing CYP199A2 were reported to catalyze the regioselective oxidation of 6-hydroxy-2-naphthoic acid to afford 6,7-dihydroxynaphthoic acid. It can form co-crystals with caffeine.

Flammability and Explosibility

Non flammable

Synthesis

6-Hydroxy-2-naphthoic acid [16712-64-4], mp 245 – 248℃, is synthesized by carboxylation of the potassium salt of 2-naphthol at 170 – 230℃. It couples with diazo compounds in the 5-position and undergoes sulfonation in the 4- and 7-positions.

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