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Bis-(triphenylphosphino)-cuprous borohydride

Basic information Safety Supplier Related

Bis-(triphenylphosphino)-cuprous borohydride Basic information

Product Name:
Bis-(triphenylphosphino)-cuprous borohydride
Synonyms:
  • Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD
  • Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE
  • BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE
  • bis-(triphenylphosphino)-cuprous borohydride
  • Copper bis(trimethylphosphine)(tetrahydroborate)
CAS:
16903-61-0
MF:
2C18H15P.Cu.BH4
MW:
602.97
EINECS:
240-951-0
Product Categories:
  • Cu
  • B (Classes of Boron Compounds)
  • Classes of Metal Compounds
  • Cu (Copper) Compounds
  • Reduction
  • Synthetic Organic Chemistry
  • Tetrahydroborates
  • Transition Metal Compounds
Mol File:
16903-61-0.mol
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Bis-(triphenylphosphino)-cuprous borohydride Chemical Properties

Melting point:
164 °C (dec.)(lit.)
storage temp. 
Store below +30°C.
form 
powder to crystal
color 
White to Almost white
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference
16903-61-0(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-15
Safety Statements 
26-60-43-37-7/8
RIDADR 
2813
WGK Germany 
3
9-21
HazardClass 
4.3
PackingGroup 
III
HS Code 
29319019

MSDS

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Bis-(triphenylphosphino)-cuprous borohydride Usage And Synthesis

Uses

Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes.

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