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4-(Dimethylamino)benzophenone

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4-(Dimethylamino)benzophenone Basic information

Product Name:
4-(Dimethylamino)benzophenone
Synonyms:
  • (4-Dimethylamino-phenyl)-phenyl-methanone
  • [4-(Dimethylamino)phenyl](phenyl)methanone
  • [4-(dimethylamino)phenyl]phenyl-methanon
  • [4-(Dimethylamino)phenyl]phenylmethanone
  • 4-Dimethylaminobenzophenon
  • Benzenamine,N,N-dimethyl-4-(phenylmethanone)-
  • Benzophenone, 4-(dimethylamino)-
  • Methanone,[4-(dimethylamino)phenyl]phenyl-
CAS:
530-44-9
MF:
C15H15NO
MW:
225.29
EINECS:
208-478-4
Product Categories:
  • Aromatic Benzophenones & Derivatives (substituted)
  • Amine Photochemical CoinitiatorsPolymerization Initiators
  • Benzophenone
  • Organic Photoinitiators
  • Polymer Science
  • Polymerization Initiators
Mol File:
530-44-9.mol
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4-(Dimethylamino)benzophenone Chemical Properties

Melting point:
88-90 °C(lit.)
Boiling point:
250 °C / 15mmHg
Density 
1.0463 (rough estimate)
refractive index 
1.5200 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
powder to crystal
pka
2.12±0.12(Predicted)
color 
White to Light yellow to Green
Water Solubility 
insoluble
Merck 
14,3233
InChIKey
BEUGBYXJXMVRFO-UHFFFAOYSA-N
CAS DataBase Reference
530-44-9(CAS DataBase Reference)
NIST Chemistry Reference
Methanone, [4-(dimethylamino)phenyl]phenyl-(530-44-9)
EPA Substance Registry System
Methanone, [4-(dimethylamino)phenyl]phenyl- (530-44-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
29223900

MSDS

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4-(Dimethylamino)benzophenone Usage And Synthesis

Chemical Properties

YELLOW CRYSTALLINE POWDER OR CRYSTALS

Uses

4-(Dimethylamino)benzophenone is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.

Synthesis Reference(s)

Synthesis, p. 544, 1986 DOI: 10.1055/s-1986-31696
Tetrahedron Letters, 34, p. 7595, 1993 DOI: 10.1016/S0040-4039(00)60409-4

Purification Methods

Crystallise the pale green p-dimethylaminobenzophenone from EtOH. Dissolve 100g in 600mL of boiling EtOH, add 5g of charcoal, cool, isolate the solid by centrifugation and similarly wash the pale crystals with ice-cold EtOH. When filtered by suction, EtOH solution remains on the crystals and turns deep green in air. Dry it in a vacuum and store it in the dark. The hydrazone has m 128-130o and forms a ketyl with potassium. [Hurd & Webb Org Synth Coll Vol I 217 1941, Beilstein 14 H 82, 14 I 288, 14 III 218, 14 IV 248.]

4-(Dimethylamino)benzophenone Preparation Products And Raw materials

Raw materials

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