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HEXABUTYLDITIN

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HEXABUTYLDITIN Basic information

Product Name:
HEXABUTYLDITIN
Synonyms:
  • 1,1,1,2,2,2-Hexabutyl-distannane
  • Distannane,hexabutyl-
  • Hexa-n-butyldizinn
  • BIS(TRIBUTYLTIN)
  • BIS[TRIBUTYLTIN(IV)]
  • BIS(TRI-N-BUTYLTIN)
  • ditin
  • Hexa-n-butyL
CAS:
813-19-4
MF:
C24H54Sn2
MW:
580.11
EINECS:
212-383-3
Product Categories:
  • organotin compound
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Typical Metal Compounds
  • 813-19-4
Mol File:
813-19-4.mol
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HEXABUTYLDITIN Chemical Properties

Boiling point:
197-198 °C (10 mmHg)
Density 
1.148 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.512(lit.)
Flash point:
124°C
storage temp. 
Inert atmosphere,2-8°C
solubility 
Methanol (Slightly)
form 
liquid
Specific Gravity
1.148
color 
colorless to yellow
Water Solubility 
Immiscible with water.
Sensitive 
Air & Moisture Sensitive
BRN 
3605476
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
813-19-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
21-25-36/38-48/23/25-50/53
Safety Statements 
35-36/37/39-45-60-61
RIDADR 
UN 2788 6.1/PG 1
WGK Germany 
3
1-10
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
29319019

MSDS

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HEXABUTYLDITIN Usage And Synthesis

Chemical Properties

Clear colorless to slightly yellow liquid

Uses

Hexabutylditin (CAS# 813-19-4) is a building block used to synthesize stannylation of aryl halides, or to prepare functionalized arylstannates via Pd-catalyzed cross-coupling reactions.

Purification Methods

Purify it by distilling it in a vacuum and store it in the dark. [Shirai et al. Yakugaku Zasshi 90 59 1970, Chem Abstr 72 90593 1970, Beilstein 4 I 590.]

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